Microscopic evidence for Au-adatom-induced self-assembly of alkanethiolate species on the
Au (111) surface is presented. Based on STM measurements and density-functional theory …

Biomolecular condensates are phase separated systems that play an important role in the
spatio-temporal organisation of cells. Their distinct physico-chemical nature offers a unique …

We herein report the preparation of high refractive index polymers (HRIPs) with enhanced
thermal stability from the copolymerization of S8 and divinylbenzene (DVB) in a single step …

Both density functional theory (DFT)(B3LYP) and CCSD ab initio calculations were
employed in a theoretical investigation of the mechanism of thiolate− disulfide exchange …

The B3LYP variant of DFT has been used to study the mechanism of S− S bond scission in
dimethyl disulfide by a phosphorus nucleophile, trimethylphospine (TMP). The reaction is …

Liquid-repellent coatings with rapid self-healing and strong substrate adhesion have
tremendous potential for industrial applications, but their formulation is challenging. We …

Selenium based diaryl dichalcogenides are compounds that are receiving attention in
organic synthesis as eco‐friendly oxidation agents as well as in pharmaceutical chemistry …

Reversible protein S-nitrosylation, defined as the covalent addition of a nitroso moiety to the
reactive thiol group on a cysteine residue, has received increasing recognition as a critical …

The effect of amines on the kinetics and efficacy of radical-mediated thiol–ene coupling
(TEC) reactions was investigated. By varying the thiol reactant and amine additive, it was …

In chemical science, the vertical ionization potential (VIP) is a crucial metric for
understanding the electronegativity, hardness and softness of chemical material systems as …