Assembly of molecular building blocks into integrated complex functional molecular systems: structuring matter made to order

Z Hassan, Y Matt, S Begum… - Advanced Functional …, 2020 - Wiley Online Library
Function‐inspired design of molecular building blocks for their assembly into complex
systems has been an objective in engineering nanostructures and materials modulation at …

Incorporation of an A1/A2-difunctionalized pillar [5] arene into a metal–organic framework

NL Strutt, D Fairen-Jimenez, J Iehl… - Journal of the …, 2012 - ACS Publications
An efficient synthetic route to an A1/A2-difunctionalized pillar [5] arene containing resolvable
planar chirality has been developed and the arene employed as a strut in the synthesis of …

Synthesis of ExnBox Cyclophanes

JC Barnes, M Juricek, NA Vermeulen… - The Journal of …, 2013 - ACS Publications
A rapid and efficient synthesis of the extended bipyridinium-based class of cyclophanes
that is, Ex n Box 4+(n= 0–3), where n is the number of p-phenylene rings inserted between …

Efficient Long-Range Stereochemical Communication and Cooperative Effects in Self-Assembled Fe4L6 Cages

N Ousaka, S Grunder, AM Castilla… - Journal of the …, 2012 - ACS Publications
A series of large, optically active Fe4L6 cages was prepared from linear 5, 5′-bis (2-
formylpyridines) incorporating varying numbers (n= 0–3) of oligo-p-xylene spacers, chiral …

Molecular gauge blocks for building on the nanoscale

S Grunder, C Valente, AC Whalley… - … A European Journal, 2012 - Wiley Online Library
Molecular gauge blocks, based on 1–7, 9–11 paraxylene rings, have been synthesized as
part of a homologous series of oligoparaxylenes (OPXs) with a view to providing a molecular …

Simultaneous Suppression of π-and σ-Transmission in π-Conjugated Molecules

MH Garner, GC Solomon - The Journal of Physical Chemistry …, 2020 - ACS Publications
Molecular dielectric materials require ostensibly conflicting requirements of high
polarizability and low conductivity. As previous efforts toward molecular insulators focused …

Diverse Multi‐Functionalized Oligoarenes and Heteroarenes for Porous Crystalline Materials

S Grosjean, Z Hassan, C Wöll… - European Journal of …, 2019 - Wiley Online Library
A modular synthesis of multi‐functionalized biphenyl, terphenyl and higher linear
oligophenylene dicarboxylic acids and pyridine‐terminated oligoarenes by stepwise …

Synthesis of Functionalized Azobiphenyl‐and Azoterphenyl‐Ditopic Linkers: Modular Building Blocks for Photoresponsive Smart Materials

S Grosjean, P Hodapp, Z Hassan, C Wöll… - …, 2019 - Wiley Online Library
Modular synthesis of structurally diverse functionalized azobiphenyls and azoterphenyls for
the realization of optically switchable materials has been described. The corresponding …

Expanding the Role of Viologens in Supramolecular Chemistry through Radical-Based Integrated Materials and as Hosts for Polycyclic Aromatic Hydrocarbons

JC Barnes - 2014 - search.proquest.com
The natural world relies on molecular recognition and the processes of self-assembly in
order to organize individual components and develop them into more ordered systems and …