Transformations of organonitriles play an important role in both the laboratory and industry
due to their well-recognized chemical versatility. In particular, in organic chemistry the …

In whatever state of bonding–whether covalent to an organic residue or a heteroatom, or
polar to ionic in contact with a metal–the azide moiety N3 is characterized by its high …

Catalyst deactivation caused by the aggregation of active metal species in the reaction
process poses great challenges for practical applications of supported metal catalysts in …

An efficient method for palladium-catalyzed cross-coupling of aryl chlorides and triflates with
sodium cyanate is reported. The protocol allows for the synthesis of unsymmetrical N, N′-di …

The palladium-catalyzed three-component coupling reaction (TCCR) of aryl isocyanides,
allyl methyl carbonate, and trimethylsilyl azide was conducted in the presence of Pd2 (dba) …

The isomorphous partial substitution of Zn2+ ions in the secondary building unit (SBU) of
MFU‐4l leads to frameworks with the general formula [MxZn (5–x) Cl4 (BTDD) 3], in which …

Abstract With Sharpless' and Meldal's discovery of the immensely supportive effect that
metal catalysis has on Huisgen's classical 1, 3‐dipolar cycloaddition, azides (RN3)–long …

Azidocarbonylation of iodoarenes with CO and NaN3, a novel Heck-type carbonylation
reaction, readily occurs in an organic solvent–H2O biphasic system to furnish aroyl azides at …

Cyanamides have been attracting many chemists because of their unique structure and
reactivity. They have been used not only as a building block for heterocyclic compounds in …

Aryliodide reagieren mit NaN 3 und CO in Gegenwart eines Pd/Xantphos‐Katalysators glatt
zu Aroylaziden (ArCON 3) in 75–92% Ausbeute. Die Reaktion läuft unter milden …