Life-like motion driven by artificial molecular machines

F Lancia, A Ryabchun, N Katsonis - Nature Reviews Chemistry, 2019 - nature.com
Essentially, all motion in living organisms emerges from the collective action of biological
molecular machines transforming chemical energy, originally harvested from light, into …

Mechanically responsive molecular crystals

P Naumov, S Chizhik, MK Panda, NK Nath… - Chemical …, 2015 - ACS Publications
Transformation of energy into motion (work) is one of the basic processes of energy
conversion in nature. The processes of actuation underlying the transduction of light …

Leveraging crystalline and amorphous states of a metal‐organic complex for transformation of the photosalient effect and positive‐negative photochromism

YJ Ma, G Xiao, X Fang, T Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Uncovering differences between crystalline and amorphous states in molecular solids would
both promote the understanding of their structure–property relationships, as well as inform …

Vinylene‐linked covalent organic frameworks by base‐catalyzed aldol condensation

A Acharjya, P Pachfule, J Roeser… - Angewandte Chemie …, 2019 - Wiley Online Library
Two 2D covalent organic frameworks (COFs) linked by vinylene (− CH= CH−) groups (V‐
COF‐1 and V‐COF‐2) are synthesized by exploiting the electron deficient nature of the …

An autonomous actuator driven by fluctuations in ambient humidity

H Arazoe, D Miyajima, K Akaike, F Araoka, E Sato… - Nature materials, 2016 - nature.com
Devices that respond to negligibly small fluctuations in environmental conditions will be of
great value for the realization of more sustainable, low-power-consumption actuators and …

Controlling motion at the nanoscale: rise of the molecular machines

JM Abendroth, OS Bushuyev, PS Weiss, CJ Barrett - ACS nano, 2015 - ACS Publications
As our understanding and control of intra-and intermolecular interactions evolve, ever more
complex molecular systems are synthesized and assembled that are capable of performing …

Photoreactive crystals exhibiting [2+ 2] photocycloaddition reaction and dynamic effects

BB Rath, JJ Vittal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Conducting a reaction in the solid state eliminates the usage of solvents. If such
reactions are conducted in a single-crystal to single-crystal (SCSC) fashion, then structural …

Engineering photomechanical molecular crystals to achieve extraordinary expansion based on solid-state [2+ 2] photocycloaddition

TY Xu, F Tong, H Xu, MQ Wang, H Tian… - Journal of the American …, 2022 - ACS Publications
Photomechanical molecular crystals are promising candidates for photoactuators and can
potentially be implemented as smart materials in various fields. Here, we synthesized a new …

Manipulating light‐induced dynamic macro‐movement and static photonic properties within 1D isostructural hydrogen‐bonded molecular cocrystals

S Li, B Lu, X Fang, D Yan - Angewandte Chemie International …, 2020 - Wiley Online Library
Smart molecular crystals with light‐driven mechanical responses have received interest
owing to their potential uses in molecular machines, artificial muscles, and biomimetics …

In situ observation of a stepwise [2+ 2] photocycloaddition process using fluorescence spectroscopy

MF Wang, YH Deng, YX Hong, JH Gu, YY Cao… - Nature …, 2023 - nature.com
Using highly sensitive and selective in situ techniques to investigate the dynamics of
intermediates formation is key to better understand reaction mechanisms. However …