Derivatized benzothiazoles as two-photon-absorbing organic photosensitizers active under near infrared light irradiation

BK Kundu, G Han, Y Sun - Journal of the American Chemical …, 2023 - ACS Publications
Homogeneous organic photocatalysis typically requires molecular photosensitizers
absorbing in the ultraviolet–visible (UV/vis) region, because UV/vis photons possess the …

Donor–acceptor–acceptor-conjugated dual-state emissive acrylonitriles: investigating the effect of acceptor unit order and biological imaging

X Zhu, L Feng, S Cao, J Wang, G Niu - Organic Letters, 2022 - ACS Publications
The effect of acceptor unit order on the photophysical properties of two distinct donor–
acceptor–acceptor conjugated fluorescent acrylonitriles, TPA-AN-PhBT and TPA-BT-ANPh …

Oxidative C–H homocoupling of push–pull benzothiazoles: an atom-economical route to highly emissive quadrupolar arylamine-functionalized 2, 2 …

P Osusky, J Nociarová, M Smolicek, R Gyepes… - Organic …, 2021 - ACS Publications
Copper (II)-catalyzed C–H/C–H coupling of dipolar 2-H-benzothiazoles end-capped with
triphenylamine moieties affords highly fluorescent 2, 2′-bibenzothiazoles with quadrupolar …

Conformational emissive states in dual-state emitters with benzotriazole acceptors

LA Rodríguez-Cortés, FJ Hernández, M Rodríguez… - Matter, 2023 - cell.com
Summary Dual-state emission (DSE), the emission of organic molecules in solution and
solid state, has recently drawn interest for advanced performance materials. Here, we report …

Suitability of alkyne donor-π-donor-π-donor scaffolds for electrofluorochromic and electrochromic use

M Wałęsa-Chorab, K Muras, HL Filiatrault… - Journal of Materials …, 2022 - pubs.rsc.org
A series of electroactive materials consisting of an aromatic core that was conjugated with
two alkynes and flanked with two triphenyl amines was investigated as electrochromes and …

Synthesis and Spectral Properties of Aggregation-Induced Emission-Active Push–Pull Chromophores Based On Isoindole Scaffolds

C Yu, X Fang, Q Wu, X Guo, N Chen, C Cheng… - Organic …, 2022 - ACS Publications
A new class of tailor-made push–pull isoindole fluorophores has been synthesized through
the combination of Suzuki coupling and Knoevenagel reactions. The efficient synthetic …

Exploring solvent and substituent effects on the excited state dynamics and symmetry breaking of quadrupolar triarylamine end-capped benzothiazole chromophores …

M Fakis, V Petropoulos, P Hrobárik… - The Journal of …, 2022 - ACS Publications
We investigate herein the excited state dynamics and symmetry breaking processes in three
benzothiazole-derived two-photon absorbing chromophores by femtosecond fluorescence …

Experimental upper bounds for resonance-enhanced entangled two-photon absorption cross section of indocyanine green

M He, BP Hickam, N Harper, SK Cushing - The Journal of Chemical …, 2024 - pubs.aip.org
Resonant intermediate states have been proposed to increase the efficiency of entangled
two-photon absorption (ETPA). Although resonance-enhanced ETPA (r-ETPA) has been …

Effects of two electron-donating and/or-withdrawing substituents on two-photon absorption for diphenylacetylene derivatives

S Watanabe, A Tahara, T Isozaki… - The Journal of …, 2023 - ACS Publications
Two-photon absorption for diphenylacetylene (DPA) derivatives with two substituents (−
OMe and/or− NO2) at the 4, 4′-position was investigated experimentally and theoretically …

One-Pot Reductive Methylation of Nitro-and Amino-Substituted (Hetero) Aromatics with DMSO/HCOOH: Concise Synthesis of Fluorescent Dimethylamino …

P Osuský, M Smolíček, J Nociarová… - The Journal of …, 2022 - ACS Publications
One-pot reductive N, N-dimethylation of suitable nitro-and amino-substituted (hetero) arenes
can be achieved using a DMSO/HCOOH/Et3N system acting as a low-cost but efficient …