Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Mesoporous multimetallic nanospheres with exposed highly entropic alloy sites

Y Kang, O Cretu, J Kikkawa, K Kimoto, H Nara… - Nature …, 2023 - nature.com
Multimetallic alloys (MMAs) with various compositions enrich the materials library with
increasing diversity and have received much attention in catalysis applications. However …

[HTML][HTML] Phosphated IrMo bimetallic cluster for efficient hydrogen evolution reaction

X Guo, X Wan, Q Liu, Y Li, W Li, J Shui - Escience, 2022 - Elsevier
Developing low-cost, high-performance electrocatalysts for the hydrogen evolution reaction
(HER) is essential for producing hydrogen from renewable energy sources. Herein, we …

A general synthetic method for high-entropy alloy subnanometer ribbons

L Tao, M Sun, Y Zhou, M Luo, F Lv, M Li… - Journal of the …, 2022 - ACS Publications
High-entropy alloys (HEAs) are attracting intensive attention due to their broad
compositional tunability and interesting catalytic properties. However, precisely shaping the …

Noble-metal based random alloy and intermetallic nanocrystals: syntheses and applications

M Zhou, C Li, J Fang - Chemical Reviews, 2020 - ACS Publications
Precise control over the size, shape, composition, structure, and crystal phase of random
alloy and intermetallic nanocrystals has been intensively explored in technologically …

A review of recent efforts to promote dry reforming of methane (DRM) to syngas production via bimetallic catalyst formulations

IV Yentekakis, P Panagiotopoulou… - Applied Catalysis B …, 2021 - Elsevier
Dry (CO 2) reforming of methane (DRM) for syngas production, a critical feedstock for the
production of hydrogen, ammonia, and Fischer-Tropsch derived liquid energy carriers …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Nickel and palladium catalysis: Stronger demand than ever

VM Chernyshev, VP Ananikov - Acs Catalysis, 2022 - ACS Publications
Key similarities and differences of Pd and Ni in catalytic systems are discussed. Overall, Ni
and Pd catalyze a vast number of similar C–C and C–heteroatom bond-forming reactions …

Surface and interface control in nanoparticle catalysis

C Xie, Z Niu, D Kim, M Li, P Yang - Chemical reviews, 2019 - ACS Publications
The surface and interfaces of heterogeneous catalysts are essential to their performance as
they are often considered to be active sites for catalytic reactions. With the development of …