Dioxiranes: a half-century journey

TH El-Assaad, J Zhu, A Sebastian… - Organic Chemistry …, 2022 - pubs.rsc.org
Dioxiranes are multi-tasking reagents with mild and selective oxygen transfer attributes.
These oxidants are accessed from the reaction of ketones with an oxidant and are employed …

Metal-catalyzed C–H bond oxidation in the total synthesis of natural and unnatural products

VCS Santana, MCV Fernandes, I Cappuccelli… - …, 2022 - thieme-connect.com
C–H bond oxidation is a powerful means for oxygen incorporation in organic molecules. Its
use results in fast structural diversification and in a new way of thinking about retrosynthetic …

Key Roles of Nucleation and Impurity Migration Behavior in Layer Melt Crystallization: Case Study of 4, 5-Dimethyl-1, 3-dioxol-2-one

S Xu, K Zhang, B Liu, Y Wang - Crystal Growth & Design, 2023 - ACS Publications
In melt crystallization, how the cooling rate and initial concentration affect metastable zone
width (MSZW), thus altering the impurity distribution coefficient, remains elusive. To explore …

Eucryphin analog's total synthesis, anti-inflammatory activity for DNFB-induced contact hypersensitivity and structure-activity relationship

Y Zhang, J Liu, Q Yao, H Deng, C Yao, T Kang… - Journal of Molecular …, 2023 - Elsevier
Eucryphin, a natural product widely found in plants, has a variety of biological activities. In
this work, a series of eucryphin analogs were designed, synthesized, characterized and the …

Dioxirane‐Based Stereoselective and Oxidative Transformations

I Neogi, KN Parida - ChemistrySelect, 2024 - Wiley Online Library
The synthesis of chiral organic molecules is a purity‐driven research that has become an
essential part of our lives due to their applications in pharmaceuticals. Contemporary …

Total Syntheses of Highly Oxidized Natural Products

Y Wang, X Qi - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary Natural products with high oxidation states and complex chemical
skeletons exhibit diverse bioactivities due to their unique interactions with biological targets …