Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

[HTML][HTML] Integration of nanoscale zero-valent iron and functional anaerobic bacteria for groundwater remediation: a review

H Dong, L Li, Y Lu, Y Cheng, Y Wang, Q Ning… - Environment …, 2019 - Elsevier
The technology of integrating nanoscale zero-valent iron (nZVI) and functional anaerobic
bacteria has broad prospects for groundwater remediation. This review focuses on the …

Dissimilatory reduction and transformation of ferrihydrite-humic acid coprecipitates

M Shimizu, J Zhou, C Schröder, M Obst… - … science & technology, 2013 - ACS Publications
Organic matter (OM) is present in most terrestrial environments and is often found
coprecipitated with ferrihydrite (Fh). Sorption or coprecipitation of OM with Fe oxides has …

Mechanisms of chromate, selenate, and sulfate adsorption on Al-substituted ferrihydrite: implications for ferrihydrite surface structure and reactivity

CP Johnston, M Chrysochoou - Environmental science & …, 2016 - ACS Publications
Ferrihydrite is a nanocrystalline Fe (hydr) oxide and important sink for environmental
contaminants. Although Fe (hydr) oxides are rarely pure in natural systems, little is known …

Influence of humic acid imposed changes of ferrihydrite aggregation on microbial Fe (III) reduction

K Amstaetter, T Borch, A Kappler - Geochimica et Cosmochimica Acta, 2012 - Elsevier
Microbial reduction of Fe (III) minerals at neutral pH is faced by the problem of electron
transfer from the cells to the solid-phase electron acceptor and is thought to require either …

Constraining the role of iron in environmental nitrogen transformations: Dual stable isotope systematics of abiotic NO2− reduction by Fe (II) and its production of N2O

C Buchwald, K Grabb, CM Hansel… - … et Cosmochimica Acta, 2016 - Elsevier
Despite mounting evidence for biogeochemical interactions between iron and nitrogen, our
understanding of their environmental importance remains limited. Here we present an …

[HTML][HTML] Competitive incorporation of Mn and Mg in vivianite at varying salinity and effects on crystal structure and morphology

LJ Kubeneck, LK ThomasArrigo, KA Rothwell… - … et Cosmochimica Acta, 2023 - Elsevier
Vivianite, a ferrous phosphate mineral, can be an important phosphorus (P) sink in non-
sulfidic, reducing coastal sediments. The Fe in the crystal structure of vivianite can be …

Electrochemical analysis of changes in iron oxide reducibility during abiotic ferrihydrite transformation into goethite and magnetite

M Aeppli, R Kaegi, R Kretzschmar… - … science & technology, 2019 - ACS Publications
Electron transfer to ferric iron in (oxyhydr-) oxides (hereafter iron oxides) is a critical step in
many processes that are central to the biogeochemical cycling of elements and to pollutant …

Defects induced by Al substitution enhance As (V) adsorption on ferrihydrites

TGF Souza, ETF Freitas, NDS Mohallem… - Journal of Hazardous …, 2021 - Elsevier
An original rationale is proposed to explain the controversial role of aluminum, a common
substitutive element in ferrihydrite (Fh), on arsenic adsorption. The adsorption of arsenic on …

Partitioning and mobility of chromium in iron-rich laterites from an optimized sequential extraction procedure

REG Delina, JPH Perez, JA Stammeier… - Environmental …, 2024 - ACS Publications
Chromium (Cr) leached from iron (Fe)(oxyhydr) oxide-rich tropical laterites can substantially
impact downstream groundwater, ecosystems, and human health. However, its partitioning …