Molecular Crystal Engineering: Tuning Organic Semiconductor from p-type to n-type by Adjusting Their Substitutional Symmetry.
Focusing on the bottleneck of molecularly engineered organic semiconductors, a
breakthrough is made to tune the electronic properties of organic semiconductors from p …
breakthrough is made to tune the electronic properties of organic semiconductors from p …
Fluorination of Metal Phthalocyanines: Single-Crystal Growth, Efficient N-Channel Organic Field-Effect Transistors and Structure-Property Relationships
The fluorination of p-type metal phthalocyanines produces n-type semiconductors, allowing
the design of organic electronic circuits that contain inexpensive heterojunctions made from …
the design of organic electronic circuits that contain inexpensive heterojunctions made from …
Hole mobility modulation in single‐crystal metal phthalocyanines by changing the metal–π/π–π interactions
Weak intermolecular interactions in organic semiconducting molecular crystals play an
important role in determining molecular packing and electronic properties. Single crystals of …
important role in determining molecular packing and electronic properties. Single crystals of …
Density functional theory study predicts low reorganization energies for azadipyrromethene-based metal complexes
W Senevirathna, CM Daddario… - The Journal of Physical …, 2014 - ACS Publications
Small internal reorganization energy is desirable for high-performance optoelectronic
materials, as it facilitates both charge separation and charge transport. However, only a …
materials, as it facilitates both charge separation and charge transport. However, only a …
Molecular orbital-based design of π-conjugated organic materials with small internal reorganization energy: Generation of nonbonding character in frontier orbitals
WC Chen, I Chao - The Journal of Physical Chemistry C, 2014 - ACS Publications
One of the key parameters determining the rate of electron transfer is reorganization energy,
an energy associated with geometry change during electron/hole transfer between …
an energy associated with geometry change during electron/hole transfer between …
Solution-processable n-type tin phthalocyanines in organic thin film transistors and as ternary additives in organic photovoltaics
TM Grant, NA Rice, L Muccioli, F Castet… - ACS Applied …, 2019 - ACS Publications
Tin phthalocyanines have shown promise in both organic thin film transistors (OTFTs) and
organic photovoltaics (OPVs); however, no examples of solution processable axial …
organic photovoltaics (OPVs); however, no examples of solution processable axial …
Exciton dynamics in phthalocyanine molecular crystals
The exciton transport properties of an octa (butyl)-substituted metal-free phthalocyanine (H2-
OBPc) molecular crystal have been explored by means of a combined computational …
OBPc) molecular crystal have been explored by means of a combined computational …
Molecular Quadrupole Moments Promote Ground‐State Charge Generation in Doped Organic Semiconductors
The role of local environmental interactions on the generation of free charge carriers in
doped organic layers is investigated. Via a classical micro‐electrostatic model, a dual effect …
doped organic layers is investigated. Via a classical micro‐electrostatic model, a dual effect …
Importance and nature of short-range excitonic interactions in light harvesting complexes and organic semiconductors
The singlet excitonic coupling between many pairs of chromophores is evaluated in three
different light harvesting complexes (LHCs) and two organic semiconductors (amorphous …
different light harvesting complexes (LHCs) and two organic semiconductors (amorphous …
Growing ultra-flat organic films on graphene with a face-on stacking via moderate molecule-substrate interaction
The electronic properties of small molecule organic crystals depend heavily on the
molecular orientation. For multi-layer organic photovoltaics, it is desirable for the molecules …
molecular orientation. For multi-layer organic photovoltaics, it is desirable for the molecules …