Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes

M Crespo, M Martinez, SM Nabavizadeh… - Coordination Chemistry …, 2014 - Elsevier
The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

Pd-Catalyzed Monoselective ortho-C–H Alkylation of N-Quinolyl Benzamides: Evidence for Stereoretentive Coupling of Secondary Alkyl Iodides

SY Zhang, Q Li, G He, WA Nack… - Journal of the American …, 2015 - ACS Publications
We report a method for the monoselective alkylation of ortho-C–H bonds of N-quinolyl
benzamides with both primary and secondary alkyl halides under palladium catalysis. With …

The history of organoplatinum chemistry in Iran: 40-year research

RB Aghakhanpour, S Paziresh… - Journal of the Iranian …, 2020 - Springer
This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his
working years in Shiraz University, Chemistry Department, Organometallic Chemistry …

Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation …

KT Sylvester, K Wu, AG Doyle - Journal of the American Chemical …, 2012 - ACS Publications
The mechanism of a recently reported Suzuki coupling reaction of quinoline-derived allylic
N, O-acetals has been studied using a combination of structural, stereochemical, and kinetic …

Electronic Rearrangement in Steps of Reductive Elimination of Polar Electrophiles Leads to Refinement of Redox Events

K Basemann, JJ Becker, TL Windus, MR Gagné - Organometallics, 2023 - ACS Publications
The oxidative addition/reductive elimination of polar molecules such as methyl iodide at late
metal centers has a strongly supported SN2 mechanism for many key organometallic …

Mechanistic Study of the Oxidation of a Methyl Platinum(II) Complex with O2 in Water: PtIIMe-to-PtIVMe and PtIIMe-to-PtIVMe2 Reactivity

AV Sberegaeva, WG Liu, RJ Nielsen… - Journal of the …, 2014 - ACS Publications
The mechanism of oxidation by O2 of (dpms) PtIIMe (OH2)(1) and (dpms) PtIIMe
(OH)−(2)[dpms= di (2-pyridyl) methanesulfonate] in water in the pH range of 4–14 at 21° C …

Oxidative addition of MeI to some cyclometalated organoplatinum (II) complexes: Kinetics and mechanism

SM Nabavizadeh, H Amini, F Jame… - Journal of …, 2012 - Elsevier
New cyclometalated platinum (II) complexes [PtMe (C^ N) L], 1, in which C^ N=
deprotonated 2-phenylpyridine (ppy), benzo [h] quinoline (bhq) or 2-(p-tolyl) pyridine (tpy) …

Preparation and Ground-State Electronic Structure of Heterobimetallic Yb–PtIV-Alkyl Complexes

M Tricoire, G Danoun, G Nocton - Inorganic Chemistry, 2024 - ACS Publications
This article focuses on the synthesis of heterobimetallic complexes of lanthanide and
platinum. It describes the synthesis of the Cp* Yb (bipym) PtMe2 complex and its …

Secondary kinetic isotope effects in oxidative addition of benzyl bromide to dimethylplatinum (II) complexes

MD Aseman, M Rashidi, SM Nabavizadeh… - …, 2013 - ACS Publications
The secondary α-deuterium kinetic isotope effects (KIEs),(k H/k D) α, have been determined,
at different temperatures and in solvents having different polarities, for reaction of …

The mechanism of oxidative addition of iodine to a dimethylplatinum (II) complex

SM Nabavizadeh, H Amini, M Rashidi… - Journal of …, 2012 - Elsevier
The oxidative addition of iodine to [PtMe2 (bipy)], 1, occurs easily with trans stereochemistry
to give trans-[PtI2Me2 (bipy)], 2a, which then equilibrates slowly with cis-[PtI2Me2 (bipy)], 2b …