Nanoconfined ionic liquids

S Zhang, J Zhang, Y Zhang, Y Deng - Chemical Reviews, 2017 - ACS Publications
Ionic liquids (ILs) have been widely investigated as novel solvents, electrolytes, and soft
functional materials. Nevertheless, the widespread applications of ILs in most cases have …

Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis

J Dupont, BC Leal, P Lozano, AL Monteiro… - Chemical …, 2024 - ACS Publications
Ionic liquids (ILs) have unique physicochemical properties that make them advantageous for
catalysis, such as low vapor pressure, non-flammability, high thermal and chemical …

Fifteen years of supported ionic liquid phase-catalyzed hydroformylation: material and process developments

JM Marinkovic, A Riisager, R Franke… - Industrial & …, 2018 - ACS Publications
This review describes the development of supported ionic liquid phase (SILP) materials as
novel hydroformylation catalysts. Ligand-modified rhodium catalysts can be immobilized in a …

Single atom dispersed Rh-biphephos&PPh 3@ porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

C Li, L Yan, L Lu, K Xiong, W Wang, M Jiang, J Liu… - Green …, 2016 - pubs.rsc.org
A vinyl functionalized biphephos ligand with high steric hindrance was copolymerized with
tris (4-vinphenyl) phosphane and other ligands to afford efficient porous organic copolymers …

Current state of the art of the solid Rh-based catalyzed hydroformylation of short-chain olefins

S Hanf, L Alvarado Rupflin, R Gläser, SA Schunk - Catalysts, 2020 - mdpi.com
The hydroformylation of olefins is one of the most important homogeneously catalyzed
processes in industry to produce bulk chemicals. Despite the high catalytic activities and …

Preparation of catalytic materials using ionic liquids as the media and functional components

P Zhang, T Wu, B Han - Advanced Materials, 2014 - Wiley Online Library
Ionic liquids (ILs) have attracted much attention due to their unique properties and wide
application potential in a variety of fields. The unusual properties of ILs provide numerous …

Adjacent MnOx clusters enhance the hydroformylation activity of rhodium single-atom catalysts

Y Zheng, Q Yang, S Wang, S Furukawa, M Li… - Applied Catalysis B …, 2024 - Elsevier
Hydroformylation reactions promoted by Rh single-atom catalysts typically exhibit a negative
reaction order for CO and a positive reaction order for H 2 and alkenes. To enhance the …

Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of …

C Li, K Sun, W Wang, L Yan, X Sun, Y Wang, K Xiong… - Journal of …, 2017 - Elsevier
Vinyl functionalized Xantphos ligand (denoted as 4v-Xantphos) was newly synthesized and
successfully doped into the PPh 3 based porous organic polymers (POPs) through the …

Enhanced regioselectivity in propylene hydroformylation using Xantphos-modified single-atom Rh/CeO2 catalyst

Y Zheng, Q Yang, S Wang, S Furukawa, P Wang, M Li… - Journal of …, 2024 - Elsevier
Single-atom Rh catalysts have been reported to exhibit high activity in olefin
hydroformylation, yet with limited regioselectivity. We develop a Xantphos ligand …

Recent advances in applications of supported ionic liquids

P Kaur, HK Chopra - Current Organic Chemistry, 2019 - ingentaconnect.com
The supported ionic liquids have shown immense potential for numerous applications in
catalysis and separation science. In the present review, the remarkable contribution of …