Recent advances in enantioselective Pd-catalyzed allylic substitution: from design to applications

O Pamies, J Margalef, S Canellas, J James… - Chemical …, 2021 - ACS Publications
This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

Bimetallic catalysis in stereodivergent synthesis

X Huo, G Li, X Wang, W Zhang - Angewandte Chemie, 2022 - Wiley Online Library
Bimetallic catalysis has emerged as an efficient strategy for the development of new
chemical reactions. Importantly, this strategy also provides a simple and powerful platform …

Challenges and opportunities in multicatalysis

S Martínez, L Veth, B Lainer, P Dydio - ACS Catalysis, 2021 - ACS Publications
Multicatalysis is an emerging field targeting the development of efficient catalytic
transformations to quickly convert relatively simple starting materials into more complex …

Enantio-and diastereodivergent construction of 1, 3-nonadjacent stereocenters bearing axial and central chirality through synergistic Pd/Cu catalysis

J Zhang, X Huo, J Xiao, L Zhao, S Ma… - Journal of the American …, 2021 - ACS Publications
In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …

Dispersion and steric effects on enantio-/diastereoselectivities in synergistic dual transition-metal catalysis

B Li, H Xu, Y Dang, KN Houk - Journal of the American Chemical …, 2022 - ACS Publications
Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …

Stereodivergent synthesis of tertiary fluoride-tethered allenes via copper and palladium dual catalysis

SQ Yang, YF Wang, WC Zhao, GQ Lin… - Journal of the American …, 2021 - ACS Publications
Herein we describe a protocol for the unprecedented stereodivergent synthesis of tertiary
fluoride-tethered allenes bearing a stereogenic center and stereogenic axis via Cu/Pd …

Recent progress of asymmetric catalysis from a chinese perspective

YM He, YZ Cheng, Y Duan, YD Zhang, QH Fan… - CCS …, 2023 - chinesechemsoc.org
The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

Enantio‐and Diastereodivergent Synthesis of Spirocycles through Dual‐Metal‐Catalyzed [3+ 2] Annulation of 2‐Vinyloxiranes with Nucleophilic Dipoles

Y Peng, X Huo, Y Luo, L Wu, W Zhang - Angewandte Chemie, 2021 - Wiley Online Library
The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …

Asymmetric synthesis of allylic compounds via hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes

G Li, X Huo, X Jiang, W Zhang - Chemical Society Reviews, 2020 - pubs.rsc.org
Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

Dual-Catalyzed Stereodivergent Electrooxidative Homocoupling of Benzoxazolyl Acetate

J Zhang, W Zhu, Z Chen, Q Zhang… - Journal of the American …, 2024 - ACS Publications
The development of a reliable strategy for stereodivergent radical reactions that allows
convenient access to all stereoisomers of homocoupling adducts with multiple stereogenic …