Heterogeneous catalyst discovery using 21st century tools: a tutorial

EJ Ras, G Rothenberg - RSC Advances, 2014 - pubs.rsc.org
In this tutorial we highlight the optimal working methodology for discovering novel
heterogeneous catalysts using modern tools. First, we give a structure to the discovery and …

High‐Throughput Heterogeneous Catalytic Science

RJ Hendershot, CM Snively… - Chemistry–A European …, 2005 - Wiley Online Library
High‐throughput experimentation in heterogeneous catalysis has recently experienced
nearly exponential growth. Initial qualitative screening has evolved into quantitative high …

A Simple and Efficient Device and Method for Measuring the Kinetics of Gas‐Producing Reactions

TK Slot, NR Shiju, G Rothenberg - … Chemie International Edition, 2019 - Wiley Online Library
We present a new device for quantifying gases or gas mixtures based on the simple
principle of bubble counting. With this device, we can follow reaction kinetics down to …

Topological mapping of bidentate ligands: a fast approach for screening homogeneous catalysts

E Burello, G Rothenberg - Advanced Synthesis & Catalysis, 2005 - Wiley Online Library
The challenge of predicting the catalytic properties of large libraries of homogeneous
catalysts is introduced. A new concept is presented that combines fundamental chemical …

Optimal Heck cross‐coupling catalysis: a pseudo‐pharmaceutical approach

E Burello, G Rothenberg - Advanced Synthesis & Catalysis, 2003 - Wiley Online Library
The problem of predicting the activity of ligands and solvents in homogeneous catalysis is
addressed. A systematic selection method for ligands and solvents is presented, using a …

Analysis of three-and four-way data using multivariate curve resolution-alternating least squares with global multi-way kinetic fitting

E Bezemer, SC Rutan - Chemometrics and intelligent laboratory systems, 2006 - Elsevier
This paper demonstrates a novel implementation of an alternating least squares (ALS)
algorithm for resolving three-and four-way data. Computer-simulated multi-way data are …

The future, faster: roles for high-throughput experimentation in accelerating discovery in organometallic chemistry and catalysis

S Monfette, JM Blacquiere, DE Fogg - Organometallics, 2011 - ACS Publications
High-throughput experimentation has enormous potential to accelerate the discovery and
implementation of new methodologies based on organometallic catalysis. A perspective is …

Time as a Dimension in High‐Throughput Homogeneous Catalysis

JM Blacquiere, T Jurca, J Weiss… - Advanced Synthesis & …, 2008 - Wiley Online Library
High‐throughput screening offers major opportunities to accelerate the discovery and
optimization of homogeneously catalyzed reactions. A general method for acquisition of …

Determination of hydroxyl rate constants by a high-throughput fluorimetric assay: towards a unified reactivity scale for antioxidants

G Louit, M Hanedanian, F Taran, H Coffigny… - Analyst, 2009 - pubs.rsc.org
We describe in this article the development of a new method for the determination of rate
constants of reaction of the hydroxyl radical, generated by radiolysis of water, with almost …

A droplet-based high-throughput tubular platform to extract rate constants of slow chemical reactions

W Engl, M Tachibana, A Colin, P Panizza - Chemical Engineering Science, 2008 - Elsevier
A high-throughput tubular millifluidic platform for performing slow kinetics measurements
occurring in liquid phase, using minute amounts of reactant is described. The method …