Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position

Y Avila, O Pérez, L Sánchez, MC Vázquez… - New Journal of …, 2023 - pubs.rsc.org
This contribution reports the preparation and thermally induced spin crossover (SCO) in the
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …

Thermally-induced spin-crossover (SCO) in Fe (4-ethynylpyrdine) 2 [Fe (CN) 5 NO]. Why is the SCO observed in 2D ferrous nitroprussides despite the NO–NC …

K Scanda, Y Avila, L Sánchez, R Mojica… - New Journal of …, 2023 - pubs.rsc.org
Pillared ferrous nitroprussides form an interesting series of coordination polymers where the
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …

Fe(L)2[M(CN)4] with L = 4-Ethyl Isonicotinate and M = Ni, Pd, Pt.─A Series of Hofmann-Type Frameworks with Spin Crossover: The Dominant Role of the Fe–NC …

MC Vázquez, JW Reid, Y Avila… - The Journal of …, 2024 - ACS Publications
This contribution reports the incorporation of an organic pillar (L), 4-ethyl isonicotinate,
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …