Cylindrical molecular brushes: Synthesis, characterization, and properties

SS Sheiko, BS Sumerlin, K Matyjaszewski - Progress in Polymer Science, 2008 - Elsevier
Brush-like macromolecules are unique polymer molecules whose conformation and
physical properties are controlled by steric repulsion of densely grafted side chains …

Stimuli-responsive molecular brushes

H Lee, J Pietrasik, SS Sheiko… - Progress in polymer …, 2010 - Elsevier
Molecular brushes are composed of a flexible backbone and densely grafted side chains.
The conformation of molecular brushes is governed by side chains separated by a distance …

Molecular structure of bottlebrush polymers in melts

J Paturej, SS Sheiko, S Panyukov, M Rubinstein - Science advances, 2016 - science.org
Bottlebrushes are fascinating macromolecules that display an intriguing combination of
molecular and particulate features having vital implications in both living and synthetic …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Control of grafting density and distribution in graft polymers by living ring-opening metathesis copolymerization

TP Lin, AB Chang, HY Chen… - Journal of the …, 2017 - ACS Publications
Control over polymer sequence and architecture is crucial to both understanding structure–
property relationships and designing functional materials. In pursuit of these goals, we …

Standard definitions of persistence length do not describe the local “intrinsic” stiffness of real polymer chains

HP Hsu, W Paul, K Binder - Macromolecules, 2010 - ACS Publications
On the basis of extensive Monte Carlo simulations of lattice models for linear chains under
good and Θ solvents conditions, and for bottle-brush polymers under good solvent …

Effects of grafting density on block polymer self-assembly: From linear to bottlebrush

TP Lin, AB Chang, SXL Luo, HY Chen, B Lee… - ACS …, 2017 - ACS Publications
Grafting density is an important structural parameter that exerts significant influences over
the physical properties of architecturally complex polymers. In this report, the physical …

Dilute solution structure of bottlebrush polymers

S Dutta, MA Wade, DJ Walsh, D Guironnet, SA Rogers… - Soft Matter, 2019 - pubs.rsc.org
Bottlebrush polymers are a class of macromolecules that have recently found use in a wide
variety of materials, ranging from lubricating brushes and nanostructured coatings to …

Conformation of cylindrical brushes in solution: effect of side chain length

B Zhang, F Gröhn, JS Pedersen, K Fischer… - …, 2006 - ACS Publications
The conformation of cylindrical brush polymers with a polymethacrylate main and
polystyrene side chains (6≤≤ 33, with the number-average degree of polymerization of the …

Conformation of a comb-like chain free in solution and confined in a nanochannel: from linear to bottlebrush structure

Z Tang, X Pan, H Zhou, L Li, M Ding - Macromolecules, 2022 - ACS Publications
We study the conformation of a comb-like polymer chain in dilute solution from being in a
free state to being confined in a nanochannel by using Brownian dynamics simulations. In …