Site-predictable and chemoselective C–H bond functionalization reactions offer synthetically
powerful strategies for the step-economic diversification of both feedstock and fine …

Organic semiconductors have received broad attention and research interest due to their
unique integration of semiconducting properties with structural tunability, intrinsic flexibiltiy …

Single-atom catalysts (SACs) have well-defined active sites, making them of potential
interest for organic synthesis,,–. However, the architecture of these mononuclear metal …

Conspectus Transition-metal-catalyzed reductive coupling of electrophiles has emerged as
a powerful tool for the construction of molecules. While major achievements have been …

Cu-mediated Ullmann-type cross-coupling has experienced significant advances over the
last century since the seminal publication by Ullmann in 1901. These advances have …

Cross-coupling platforms are traditionally built around a sequence of closed-shell steps,
such as oxidative addition, transmetalation, and reductive elimination. Herein, we describe a …

In contrast with the well-established enantioconvergent radical C (sp 3)–C cross-coupling of
racemic secondary alkyl electrophiles, the corresponding coupling of tertiary electrophiles to …

Metal-catalyzed cross-electrophile couplings have become a valuable tool for carbon–
carbon bond formation. This minireview provides a comprehensive overview of the recent …

Cross-couplings and related reactions are a class of highly efficient synthetic protocols that
are generally promoted by molecular Pd species as catalysts. However, catalysts based on …

The enantioconvergent cross-coupling of racemic alkyl halides represents a powerful tool for
the synthesis of enantioenriched molecules. In this regard, the first-row transition metal …