Catalyzing electrosynthesis: a homogeneous electrocatalytic approach to reaction discovery

JC Siu, N Fu, S Lin - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemistry has been used as a tool to drive chemical reactions for over
two centuries. With the help of an electrode and a power source, chemists are bestowed with …

The Huisgen reaction: milestones of the 1, 3‐dipolar cycloaddition

M Breugst, HU Reissig - Angewandte Chemie International …, 2020 - Wiley Online Library
Abstract The concept of 1, 3‐dipolar cycloadditions was presented by Rolf Huisgen 60 years
ago. Previously unknown reactive intermediates, for example azomethine ylides, were …

Manganese-Catalyzed Oxidative Azidation of C(sp3)–H Bonds under Electrophotocatalytic Conditions

L Niu, C Jiang, Y Liang, D Liu, F Bu, R Shi… - Journal of the …, 2020 - ACS Publications
The selective installation of azide groups into C (sp3)–H bonds is a priority research topic in
organic synthesis, particularly in pharmaceutical discovery and late-stage diversification …

[HTML][HTML] Recent synthetic efforts towards high energy density materials: How to design high-performance energetic structures?

J Zhou, J Zhang, B Wang, L Qiu, R Xu, AB Sheremetev - FirePhysChem, 2022 - Elsevier
Energetic material is a very essential company of compounds, widely used in various fields,
primarily in the military industry and space technologies. These compounds are unique in …

Radical cascade cyclization of 1, n-enynes and diynes for the synthesis of carbocycles and heterocycles

J Xuan, A Studer - Chemical Society Reviews, 2017 - pubs.rsc.org
Carbo-and heterocycles are widely found in natural products, biologically active structures,
medicinally relevant compounds, and in many other fine chemicals. The development of …

New strategies for the synthesis of aliphatic azides

P Sivaguru, Y Ning, X Bi - Chemical Reviews, 2021 - ACS Publications
Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

Radical-mediated strategies for the functionalization of alkenes with diazo Compounds

YL Su, GX Liu, JW Liu, L Tram, H Qiu… - Journal of the American …, 2020 - ACS Publications
One of the most common reactions of diazo compounds with alkenes is cyclopropanation,
which occurs through metal carbene or free carbene intermediates. Alternative …

Iron-catalyzed enantioselective radical carboazidation and diazidation of α, β-unsaturated carbonyl compounds

W Liu, M Pu, J He, T Zhang, S Dong, X Liu… - Journal of the …, 2021 - ACS Publications
Azidation of alkenes is an efficient protocol to synthesize organic azides which are important
structural motifs in organic synthesis. Enantioselective radical azidation, as a useful strategy …

Mn-catalyzed highly efficient aerobic oxidative hydroxyazidation of olefins: a direct approach to β-azido alcohols

X Sun, X Li, S Song, Y Zhu, YF Liang… - Journal of the American …, 2015 - ACS Publications
An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-
azido alcohols has been developed. The aerobic oxidative generation of azido radical …

Synthesis of quinoxalines through Cu-electrocatalytic azidation/annulation cascade at low catalyst loading

M Baidya, S De Sarkar - Organic Letters, 2023 - ACS Publications
A Cu-electrocatalytic azidation of N-aryl enamines and subsequent denitrogenative
annulation for the construction of quinoxaline frameworks is reported. Only 0.5 mol% of …