Stimuli responsive dynamic transformations in supramolecular gels

S Panja, DJ Adams - Chemical Society Reviews, 2021 - pubs.rsc.org
Supramolecular gels are formed by the self-assembly of small molecules under the
influence of various non-covalent interactions. As the interactions are individually weak and …

Advances in frontal polymerization strategy: From fundamentals to applications

Q Li, HX Shen, C Liu, CF Wang, L Zhu… - Progress in Polymer …, 2022 - Elsevier
Polymer materials have sparked considerable interest from both academic and industrial
researchers due to their fantastic features and wide applications. The polymer synthetic …

From responsive to adaptive and interactive materials and materials systems: A roadmap

A Walther - Advanced Materials, 2020 - Wiley Online Library
Soft matter systems and materials are moving toward adaptive and interactive behavior,
which holds outstanding promise to make the next generation of intelligent soft materials …

From dynamic self-assembly to networked chemical systems

BA Grzybowski, K Fitzner, J Paczesny… - Chemical Society …, 2017 - pubs.rsc.org
Although dynamic self-assembly, DySA, is a relatively new area of research, the past
decade has brought numerous demonstrations of how various types of components–on …

ATP‐responsive and ATP‐fueled self‐assembling systems and materials

J Deng, A Walther - Advanced Materials, 2020 - Wiley Online Library
Adenosine triphosphate (ATP) is a central metabolite that plays an indispensable role in
various cellular processes, from energy supply to cell‐to‐cell signaling. Nature has …

Feedback-induced temporal control of “breathing” polymersomes to create self-adaptive nanoreactors

H Che, S Cao, JCM Van Hest - Journal of the American Chemical …, 2018 - ACS Publications
Here we present the development of self-regulated “breathing” polymersome nanoreactors
that show temporally programmable biocatalysis induced by a chemical fuel. pH-sensitive …

Programmable dynamic steady states in ATP-driven nonequilibrium DNA systems

L Heinen, A Walther - Science advances, 2019 - science.org
Inspired by the dynamics of the dissipative self-assembly of microtubules, chemically fueled
synthetic systems with transient lifetimes are emerging for nonequilibrium materials design …

Photoswitchable gating of non-equilibrium enzymatic feedback in chemically communicating polymersome nanoreactors

O Rifaie-Graham, J Yeow, A Najer, R Wang, R Sun… - Nature Chemistry, 2023 - nature.com
The circadian rhythm generates out-of-equilibrium metabolite oscillations that are controlled
by feedback loops under light/dark cycles. Here we describe a non-equilibrium nanosystem …

Autocatalysis: Kinetics, mechanisms and design

AI Hanopolskyi, VA Smaliak, AI Novichkov… - …, 2021 - Wiley Online Library
The importance of autocatalysis spans from practical applications such as in chemically
amplified photoresists, to autocatalysis playing a fundamental role in evolution as well as a …

Antagonistic enzymes in a biocatalytic pH feedback system program autonomous DNA hydrogel life cycles

L Heinen, T Heuser, A Steinschulte, A Walther - Nano Letters, 2017 - ACS Publications
Enzymes regulate complex functions and active behavior in natural systems and have
shown increasing prospect for developing self-regulating soft matter systems. Striving for …