Although a linear relationship between the optical activity (normally the CD signal) and the
enantiomeric excess (ee) of chiral auxiliaries has been the most commonly observed …

Comprehensive Summary Knowledge of asymmetric catalytic reaction mechanism is very
important for rational design and synthesis of new chiral catalysts or catalytic systems with …

Photocatalysts with rich S vacant gC 3 N 4@ CuIn 5 S 8 hollow heterojunction are
assembled through a facile strategy. The S vacancy is realized by rapid heating method …

Metal-catalyzed propargylic transformations represent a powerful tool in organic synthesis to
achieve new carbon–carbon and carbon–heteroatom bonds. However, detailed knowledge …

Herein, we report the development of a method for highly regio‐, stereo‐, and
enantioselective B− H bond insertion reactions of α‐silylcarbenes generated from 1 …

Photocatalytic conversion of carbon dioxide (CO 2) to fuel or useful chemicals is of great
significance for energy and environmental issues. Herein, we successfully prepare a hollow …

Catalytic formation of a regio-and enantioselective C–F bond chiral center from readily
available alkenes is a crucial goal, yet it continues to pose significant challenges in organic …

Achieving the goal of carbon neutralization using photocatalytic CO2 reduction has
garnered widespread attention. However, rapid photogenerated charge recombination …

N− C axially chiral compounds have emerged recently as appealing motifs for drug design.
However, the enantioselective synthesis of such molecules is still poorly developed and …

Developing highly efficient catalytic protocols for C–sp (3)–H bond aerobic oxidation under
mild conditions is a long-desired goal of chemists. Inspired by nature, a biomimetic …