Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th
century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility …

Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …

The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

Described is a cross-electrophilic, deaminative coupling strategy harnessing Katritzky salts
as a new species of electrophile in Ni/photoredox dual catalytic reductive cross-coupling …

Conspectus The development of homogeneous catalysts is strongly connected to the design
of new, sophisticated ligands, which resolve limitations of a given reaction protocol by …

This report describes the chemoselective coupling of polyfluoroarenes with aryl germanes in
the presence of aromatic C–I, C–Br, C–Cl, C–OTf, and C–SiMe3 groups, as well as …