Near-infrared metal agents assisting precision medicine: from strategic design to bioimaging and therapeutic applications

C Li, Y Pang, Y Xu, M Lu, L Tu, Q Li… - Chemical Society …, 2023 - pubs.rsc.org
Metal agents have made incredible strides in preclinical research and clinical applications in
recent years, but their short emission/absorption wavelengths continue to be a barrier to …

Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Heterocyclic nanographenes and other polycyclic heteroaromatic compounds: synthetic routes, properties, and applications

M Stepien, E Gonka, M Żyła, N Sprutta - Chemical reviews, 2017 - ACS Publications
Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic
nanographenes) are a highly versatile class of organic materials, applicable as functional …

Annulated isomeric, expanded, and contracted porphyrins

T Sarma, PK Panda - Chemical Reviews, 2017 - ACS Publications
Compared to porphyrin, its isomeric, expanded, and contracted analogues are less well
explored. This contrast is found to be even more drastic in the case of their peripherally …

Triply linked porphyrinoids

T Tanaka, A Osuka - Chemistry–A European Journal, 2018 - Wiley Online Library
Triply linked porphyrin arrays, so called porphyrin tapes, are intriguing molecules in terms of
their planar structures, far red‐shifted absorption bands, multi‐charge storage abilities, and …

Acid Catalysis via Acid‐Promoted Electron Transfer

S Fukuzumi, YM Lee, W Nam - Bulletin of the Korean Chemical …, 2020 - Wiley Online Library
This feature article focuses on acid catalysis in various redox reactions of not only organic
compounds but also metal complexes, in particular metal‐oxygen complexes via acid …

Bandgap engineering in π-extended pyrroles. A modular approach to electron-deficient chromophores with multi-redox activity

H Zhylitskaya, J Cybinska, P Chmielewski… - Journal of the …, 2016 - ACS Publications
A family of bandgap-tunable pyrroles structurally related to rylene dyes was computationally
designed and prepared using robust, easily scalable chemistry. These pyrroles show highly …

Expanded Porphyrins as Two-Dimensional Porous Membranes for CO2 Separation

Z Tian, S Dai, D Jiang - ACS Applied Materials & Interfaces, 2015 - ACS Publications
Porphyrin-based two-dimensional polymers have uniform micropores and close to atom-thin
thicknesses, but they have not been explored for gas separation. Herein we design various …

A Triply Linked Porphyrin‐Norcorrole Hybrid with Singlet Diradical Character

K Wang, S Ito, S Ren, D Shimizu… - Angewandte Chemie …, 2024 - Wiley Online Library
Norcorrole Ni (II) complexes have recently received considerable attention because they are
readily accessible antiaromatic molecules. Their high stability under ambient conditions and …

Near‐Infrared‐III‐Absorbing and‐Emitting Dyes: Energy‐Gap Engineering of Expanded Porphyrinoids via Metallation

Y Wang, K Ogasahara, D Tomihama… - Angewandte …, 2020 - Wiley Online Library
The synthesis of organometallic complexes of modified 26π‐conjugated hexaphyrins with
absorption and emission capabilities in the third near‐infrared region (NIR‐III) is described …