Living anionic addition reaction of 1, 1-diphenylethylene derivatives: one-pot synthesis of ABC-type chain-end sequence-controlled polymers

K Takahata, N Aizawa, M Nagao… - Journal of the …, 2021 - ACS Publications
In this study, a 1: 1 addition reaction using 1, 1-diphenylethylene (DPE) derivatives, referred
to as the “living anionic addition reaction”, was established to regulate the sequence of vinyl …

Effect of Block Number and Weight Fraction on the Structure and Properties of Poly(butylene terephthalate)-block-Poly(tetramethylene oxide) Multiblock Copolymers

H Xie, H Lu, Z Zhang, X Li, X Yang, Y Tu - Macromolecules, 2021 - ACS Publications
We report here the influence of block number and polyester weight fraction on the properties
of a series of poly (ether ester) multiblock copolymers (mBCPs), poly (butylene …

Introducing mechanochemistry into rubber processing: green-functionalized cross-linking network of butadiene elastomer

S Zhang, L Han, H Bai, C Li, X Wang… - ACS Sustainable …, 2021 - ACS Publications
Mechanochemistry has injected new vitality into the chemical synthesis process in the solid
state as a new, cleaner synthetic technology. Here, to overcome a series of problems …

Synthesis, kinetic study and characterization of living anionic polymerized polystyrene in cyclohexane

MR Jozaghkar, F Ziaee, SM Jalilian - Iranian Polymer Journal, 2022 - Springer
In this study, living anionic polymerization of styrene with varying molecular weights and
narrow polydispersity index was successfully carried out at 45° C in cyclohexane as a …

One-Pot Synthesis of an ABCD-type Multifunctionalized Chain-End Sequence-Controlled Polymer through “Living Anionic Addition Reaction” Using 1, 1 …

K Takahata, T Nishijima, M Suzuki, N Aizawa… - …, 2025 - ACS Publications
A repeating 1: 1 addition reaction using 1, 1-diphenylethylene (DPE) derivatives, known as
“living anionic addition reaction (LAAR),” was performed to construct defect-free DPE …

Anionic Self-alternating Polymerization of 1-(4-Vinylphenyl)-1-phenylethylene

H Kim, R Goseki, T Ishizone - Macromolecules, 2022 - ACS Publications
A new AB-type difunctional monomer, 1-(4-vinylphenyl)-1-phenylethylene (1), was subjected
to anionic polymerization using sec-butyllithium (s-BuLi), diphenylmethyllithium (Ph2CHLi) …

Synthesis of Linear and Cyclic Discrete Oligomers with Defined Sequences via Efficient Anionic Coupling Reaction

Z Guo, J He - Macromolecules, 2022 - ACS Publications
We hereby report a new strategy to prepare sequence-defined discrete oligomers with
uniform molecular weight through carbanionic addition and coupling reactions using specific …

Alternating Copolymerization Realized with Alternating Transformation of Anion-Migrated Ring-Opening Polymerization and Anionic Polymerization Mechanisms

H Bai, L Han, C Li, S Zhang, X Wang, Y Yin… - …, 2021 - ACS Publications
As a kind of well-defined monomer sequence distribution, an alternating sequence endows
polymers with specific properties owing to the precisely repeating structure. In this study, we …

Characterization and kinetics study of poly (α-methyl styrene) synthesized by living anionic polymerization

M Jozaghkar, F Ziaee - Journal of Polymer Research, 2024 - Springer
In this work, poly (α-methyl styrene)(PAMS) was synthesized through living anionic
polymerization and characterized by 13C NMR, 1H NMR, GPC, TGA, DSC. The kinetics …

Synthesis and branching structure detection of long-subchain hyperbranched polymers via pyrene-labelled methodology

C Li, L Han, H Bai, S Zhang, X Wang, Y Li, H Ma - Polymer, 2022 - Elsevier
Long-subchain hyperbranched polymers (LHPs) are macromolecules with complex
topological structures that have been extensively studied by researchers. However, the …