Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Solid-state NMR investigations of extracellular matrixes and cell walls of algae, bacteria, fungi, and plants

N Ghassemi, A Poulhazan, F Deligey… - Chemical …, 2021 - ACS Publications
Extracellular matrixes (ECMs), such as the cell walls and biofilms, are important for
supporting cell integrity and function and regulating intercellular communication. These …

Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR

T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …

Biomolecular and biological applications of solid-state NMR with dynamic nuclear polarization enhancement

WY Chow, G De Paëpe, S Hediger - Chemical Reviews, 2022 - ACS Publications
Solid-state NMR spectroscopy (ssNMR) with magic-angle spinning (MAS) enables the
investigation of biological systems within their native context, such as lipid membranes, viral …

Recent developments in MAS DNP-NMR of materials

AGM Rankin, J Trébosc, F Pourpoint… - Solid State Nuclear …, 2019 - Elsevier
Solid-state NMR spectroscopy is a powerful technique for the characterization of the atomic-
level structure and dynamics of materials. Nevertheless, the use of this technique is often …

Co-factor-free aggregation of tau into seeding-competent RNA-sequestering amyloid fibrils

P Chakraborty, G Rivière, S Liu, AI de Opakua… - Nature …, 2021 - nature.com
Pathological aggregation of the protein tau into insoluble aggregates is a hallmark of
neurodegenerative diseases. The emergence of disease-specific tau aggregate structures …

Highly efficient polarizing agents for MAS‐DNP of proton‐dense molecular solids

R Harrabi, T Halbritter, F Aussenac… - Angewandte …, 2022 - Wiley Online Library
Efficiently hyperpolarizing proton‐dense molecular solids through dynamic nuclear
polarization (DNP) solid‐state NMR is still an unmet challenge. Polarizing agents (PAs) …

Computationally assisted design of polarizing agents for dynamic nuclear polarization enhanced NMR: the AsymPol family

F Mentink-Vigier, I Marin-Montesinos… - Journal of the …, 2018 - ACS Publications
We introduce a new family of highly efficient polarizing agents for dynamic nuclear
polarization (DNP)-enhanced nuclear magnetic resonance (NMR) applications, composed …

BDPA-nitroxide biradicals tailored for efficient dynamic nuclear polarization enhanced solid-state NMR at magnetic fields up to 21.1 T

D Wisser, G Karthikeyan, A Lund… - Journal of the …, 2018 - ACS Publications
Dynamic nuclear polarization (DNP) solid-state nuclear magnetic resonance (NMR) has
developed into an invaluable tool for the investigation of a wide range of materials …

TinyPols: a family of water-soluble binitroxides tailored for dynamic nuclear polarization enhanced NMR spectroscopy at 18.8 and 21.1 T

A Lund, G Casano, G Menzildjian, M Kaushik… - Chemical …, 2020 - pubs.rsc.org
Dynamic Nuclear Polarization (DNP) has recently emerged as a key method to increase the
sensitivity of solid-state NMR spectroscopy under Magic Angle Spinning (MAS). While …