Formulating Local Environment of Oxygen Mitigates Voltage Hysteresis in Li‐Rich Materials

M Zhang, L Qiu, W Hua, Y Song, Y Deng… - Advanced …, 2024 - Wiley Online Library
Li‐rich cathode materials have emerged as one of the most prospective options for Li‐ion
batteries owing to their remarkable energy density (> 900 Wh kg− 1). However, voltage …

Nonintrusive thermal-wave sensor for operando quantification of degradation in commercial batteries

Y Zeng, F Shen, B Zhang, J Lee, D Chalise… - Nature …, 2023 - nature.com
Monitoring real-world battery degradation is crucial for the widespread application of
batteries in different scenarios. However, acquiring quantitative degradation information in …

A critical analysis of chemical and electrochemical oxidation mechanisms in Li-ion batteries

EWC Spotte-Smith, S Vijay, TB Petrocelli… - The Journal of …, 2024 - ACS Publications
Electrolyte decomposition limits the lifetime of commercial lithium-ion batteries (LIBs) and
slows the adoption of next-generation energy storage technologies. A fundamental …

Modeling intercalation chemistry with multiredox reactions by sparse lattice models in disordered rocksalt cathodes

P Zhong, F Xie, L Barroso-Luque, L Huang, G Ceder - PRX Energy, 2023 - APS
Modern battery materials can contain many elements with substantial site disorder, and their
configurational state has been shown to be critical for their performance. The intercalation …

Chemical Origin of in Situ Carbon Dioxide Outgassing from a Cation-Disordered Rock Salt Cathode

TY Huang, Z Cai, MJ Crafton, R Giovine… - Chemistry of …, 2024 - ACS Publications
In situ carbon dioxide (CO2) outgassing is a common phenomenon in lithium-ion batteries
(LiBs), primarily due to parasitic side reactions at the cathode–electrolyte interface …

Oxygen Dimerization-Driven Cation Migration Induces Voltage Hysteresis in Disordered Rocksalt Cathodes

B Kim, P Zhong, Y Choi, S Anand, HM Hau… - Journal of the …, 2024 - ACS Publications
Despite the potential to increase the energy limit of Li-rich cathodes by using oxygen redox,
its practicality has been limited by the accompanying structural changes and voltage …

Nearly all-active-material cathodes free of nickel and cobalt for Li-ion batteries

E Lee, DH Lee, S Bessette, SW Park… - Energy & …, 2024 - pubs.rsc.org
The global transition to electric vehicles and large-scale energy storage systems requires
cost-effective and abundant alternatives to commercial Co/Ni-based cathodes (eg, LiNi0 …

Improved Performance of High‐Entropy Disordered Rocksalt Oxyfluoride Cathode by Atomic Layer Deposition Coating for Li‐Ion Batteries

B Zhou, S An, D Kitsche, SL Dreyer, K Wang… - Small …, 2024 - Wiley Online Library
Lithium‐excess cation‐disordered rocksalt materials are a promising class of transition
metal‐based cathodes that exhibit high specific capacity and energy density. The …

Synergistic enhancement of ion/electron transport by ultrafine nanoparticles and graphene in Li2FeTiO4/C/G nanofibers for symmetric Li-ion batteries

W Ma, Y Tang, Y Zhang, X Li, L Liu, X Wang… - Journal of Energy …, 2025 - Elsevier
Low-cost Fe-based disordered rock salt (DRX) Li 2 FeTiO 4 is capable of providing high
capacity (295 mA hg− 1) by redox activity of cations (Fe 2+/Fe 4+ and Ti 3+/Ti 4+) and …

Dialing in the Voltage Window: Reconciling Interfacial Degradation and Performance Decay for Cation-Disordered Rocksalt Cathodes

MJ Crafton, TY Huang, Z Cai, ZM Konz… - Journal of The …, 2024 - iopscience.iop.org
Li-excess, cation-disordered rocksalt (DRX) cathode materials possess promising
electrochemical properties and resource-friendly compositions, making them attractive Li-ion …