Carboxylate‐Directed C H Functionalization

G Shi, Y Zhang - Advanced Synthesis & Catalysis, 2014 - Wiley Online Library
As a widely existing functional group in organic molecules, the carboxyl group has
numerous advantageous characteristics such as great convenience for further …

The road to bis‐periazulene (cyclohepta[def]fluorene): Realizing one of the long‐standing dreams in nonalternant hydrocarbons

A Konishi, K Horii, M Yasuda - Journal of Physical Organic …, 2023 - Wiley Online Library
The chemistry of nonalternant hydrocarbons has recently experienced a considerable
resurgence. As the relationship between naphthalene and azulene shows, an important …

Transition-metal-catalyzed C–C bond-forming reactions via C–H activation for the development of fluorescent materials with practical value

K Wang, J Zhang, R Hu, C Liu, TA Bartholome… - ACS …, 2022 - ACS Publications
Fluorescent materials of practical value have attracted considerable attention because of
their important applications in the fields of bioprobes, chemosensors, organic light-emitting …

NIR‐Absorbing π‐Extended Azulene: Non‐Alternant Isomer of Terrylene Bisimide

B Pigulski, K Shoyama, F Würthner - Angewandte Chemie, 2020 - Wiley Online Library
The first planar π‐extended azulene that retains aromaticity of odd‐membered rings was
synthesized by [3+ 3] peri‐annulation of two naphthalene imides at both long‐edge sides of …

Synthesis and Properties of Carbo- and Heterocyclic Benz[a]azulenes

A Vardanyan, A Villinger, P Ehlers… - The Journal of Organic …, 2023 - ACS Publications
A new and convenient synthesis of aryl-substituted naphtho [2, 1-a] azulenes by the
combination of Suzuki–Miyaura, Sonogashira, and cycloisomerization reactions is reported …

Palladium-catalyzed double decarboxylative [3+ 2] annulation of naphthalic anhydrides with internal alkynes

C Kanganavaree, K Kantarod, T Worakul… - The Journal of …, 2024 - ACS Publications
A palladium-catalyzed [3+ 2] annulation of naphthalic anhydrides with internal alkynes has
been developed. The present protocol offers an efficient and convenient route to access a …

Ru (II)-catalysed oxidative (4+ 2) annulation of chromene and coumarin carboxylic acids with alkynes/propargylic alcohols: isolation of Ru (0) complexes

M Shankar, KCK Swamy - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Ru (II)-catalysed oxidative (4+ 2) annulation of chromene and coumarin-3-carboxylic acids
with alkynes/propargylic alcohols via sp2 C–H bond activation is reported. While the …

Regioselective and Chemodivergent Synthesis of Azulenolactones and Azulenolactams from Rhodium (III)‐Catalyzed Reactions of Azulenecarboxamides with …

SC Lee, JY Son, JY Kim, H Eom… - … Synthesis & Catalysis, 2021 - Wiley Online Library
A regioselective and chemodivergent synthetic approach for azulenolactones and
azulenolactams as a new scaffold was demonstrated through Rh (III)‐catalyzed reaction of N …

Rhodaelectro-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling of Indole-3-carboxylic Acids and Olefins via Weakly Coordinating Carboxyl Groups

J Zhang, W Xu, W Zhuang, X Chen… - The Journal of …, 2023 - ACS Publications
A rhodaelectro-catalyzed C2–H selectively decarboxylative alkenylation of 3-carboxy-1 H-
indoles employing electricity as the traceless terminal oxidant has been accomplished. The …

Carboxylic Acid Directed C–H Arylation of Azulene

ZM Png, TLD Tam, J Xu - Organic Letters, 2020 - ACS Publications
The first example of directed C–H activation for azulene is reported. A variety of 2-
arylazulenes are obtainable exclusively from 1-azulene carboxylic acids, with yields of up to …