Metal-catalyzed regiodivergent reactions allow control over regioselectivity in the synthesis
of a wide range of organic products. Starting from the same material, it is possible to prepare …

Si–B reagents, namely silylboronic esters and silylboranes, have become increasingly
attractive as versatile reagents to introduce silicon and boron atoms into organic …

Regiodivergent alkene functionalization that produces either regioisomer starting from the
same raw materials is desirable. Herein, we report a nickel‐catalyzed switchable site …

The first example of visible-light-driven reductive carboarylation of styrenes with CO2 and
aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides …

Catalytic alkene difunctionalization via Si− H and C− H activations represents an ideal atom‐
and step‐economic pathway for quick assembly of molecular complexity. We herein …

The first thiocarboxylation of styrenes and acrylates with CO2 was realized by using visible
light as a driving force and catalytic iron salts as promoters. A variety of important β …

The utilization of CO 2 as a C1 building block for the synthesis of valuable chemicals is of
great importance. The transition metal-catalyzed carboxylation of unsaturated substrates …

Bifunctional metalloporphyrins with quaternary ammonium bromides (nucleophiles) at the
meta, para, or ortho positions of meso‐phenyl groups were synthesized as catalysts for the …

The catalytic asymmetric functionalization of readily available 1, 3-dienes is highly important,
but current examples are mostly limited to the construction of tertiary chiral centers. The …

The difunctionalization of unsaturated bonds plays a vital role in the enrichment of molecular
complexity. While various catalytic methods for alkene and alkyne difunctionalization have …