The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds

DC Crans, JJ Smee, E Gaidamauskas… - Chemical reviews, 2004 - ACS Publications
Vanadium is a trace element, which may be beneficial and possibly essential in humans1
but certainly essential for some living organisms. 2r11 Metal ions and thus vanadium ions …

Structural and functional studies on model compounds of purple acid phosphatases and catechol oxidases

R Than, AA Feldmann, B Krebs - Coordination Chemistry Reviews, 1999 - Elsevier
The synthesis, single crystal X-ray crystallographic, magnetic and electrochemical
characterization of eight representative symmetric and unsymmetric complexes as structural …

A General Iron‐Catalyzed Decarboxylative Oxygenation of Aliphatic Carboxylic Acids

LM Denkler, M Aladahalli Shekar, TSJ Ngan… - Angewandte …, 2024 - Wiley Online Library
We report an iron‐catalyzed decarboxylative C (sp3)− O bond‐forming reaction under mild,
base‐free conditions with visible light irradiation. The transformation uses readily available …

A High-valent nonheme iron intermediate. Structure and properties of [Fe2 (. mu.-O) 2 (5-Me-TPA) 2](ClO4) 3

Y Dong, H Fujii, MP Hendrich, RA Leising… - Journal of the …, 1995 - ACS Publications
In our efforts to model the oxygen activation chemistry of methane monooxygenase (MMO)
and the R2 protein of ribonucleotide reductase (RNR), we have discovered a transient green …

Iron‐Catalyzed Water Oxidation: O–O Bond Formation via Intramolecular Oxo–Oxo Interaction

HT Zhang, XJ Su, F Xie, RZ Liao… - Angewandte …, 2021 - Wiley Online Library
Herein, we report the importance of structure regulation on the O− O bond formation process
in binuclear iron catalysts. Three complexes,[Fe2 (μ‐O)(OH2) 2 (TPA) 2] 4+(1),[Fe2 (μ …

Complexes with FeIII2(μ-O)(μ-OH), FeIII2(μ-O)2, and [FeIII32-O)3] Cores:  Structures, Spectroscopy, and Core Interconversions

H Zheng, Y Zang, Y Dong, VG Young… - Journal of the American …, 1999 - ACS Publications
We have synthesized the first complexes with bis (μ-oxo) diiron (III) and (μ-oxo)(μ-hydroxo)
diiron (III) cores (1 and 2, L= TPA (a), 5-Et3-TPA (b), 6-Me3-TPA (c), 4, 6-Me6-TPA (d), BQPA …

Phosphate ester hydrolysis: metal complexes as purple acid phosphatase and phosphotriesterase analogues

LR Gahan, SJ Smith, A Neves… - European journal of …, 2009 - Wiley Online Library
This microreview describes the structures and properties of a number of bimetallic
complexes designed as both structural and functional mimics of the active sites of some …

Raman Signature of the Fe2O2 “Diamond” Core

EC Wilkinson, Y Dong, Y Zang, H Fujii… - Journal of the …, 1998 - ACS Publications
We report the resonance Raman (RR) spectra of iron complexes containing the Fe2 (μ-O) 2
core. Frozen CH3CN solutions of the FeIIIFeIV intermediate [Fe2 (μ-O) 2L2](ClO4) 3 (where …

A new manganese dinuclear complex with phenolate ligands and a single unsupported oxo bridge. Storage of two positive charges within less than 500 mV …

O Horner, E Anxolabéhère-Mallart, MF Charlot… - Inorganic …, 1999 - ACS Publications
The compound [MnIII2OL2](ClO4) 2.2. 23CHCl3. 0.65 CH2Cl2 where L-is the monoanionic
N, N-bis (2-pyridylmethyl)-N '-salicyliden-1, 2-diaminoethane ligand, has been synthesized …

Structures and properties of multinuclear vanadium (III) complexes: seeking a clue to understand the role of vanadium (III) in ascidians

K Kanamori - Coordination chemistry reviews, 2003 - Elsevier
Certain ascidians accumulate vanadium (III) to a great extent in their blood cells. The role of
vanadium (III) in ascidians is still a controversial issue, though 90 years have already …