Highly oxygenated organic molecules (HOM) from gas-phase autoxidation involving peroxy radicals: A key contributor to atmospheric aerosol

F Bianchi, T Kurtén, M Riva, C Mohr… - Chemical …, 2019 - ACS Publications
Highly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation
involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on …

Recent advances in understanding secondary organic aerosol: Implications for global climate forcing

M Shrivastava, CD Cappa, J Fan… - Reviews of …, 2017 - Wiley Online Library
Anthropogenic emissions and land use changes have modified atmospheric aerosol
concentrations and size distributions over time. Understanding preindustrial conditions and …

Increasing isoprene epoxydiol-to-inorganic sulfate aerosol ratio results in extensive conversion of inorganic sulfate to organosulfur forms: implications for aerosol …

M Riva, Y Chen, Y Zhang, Z Lei, NE Olson… - … science & technology, 2019 - ACS Publications
Acid-driven multiphase chemistry of isoprene epoxydiols (IEPOX), key isoprene oxidation
products, with inorganic sulfate aerosol yields substantial amounts of secondary organic …

A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates

W Fan, T Chen, Z Zhu, H Zhang, Y Qiu, D Yin - Journal of Hazardous …, 2022 - Elsevier
Secondary organic aerosols (SOA) are crucial constitution of fine particulate matter (PM),
which are mainly derived from photochemical oxidation products of primary organic matter …

The secondary formation of organosulfates under interactions between biogenic emissions and anthropogenic pollutants in summer in Beijing

Y Wang, M Hu, S Guo, Y Wang, J Zheng… - Atmospheric …, 2018 - acp.copernicus.org
Organosulfates (OSs) with ambiguous formation mechanisms are a potential source of
missing secondary organic aerosol (SOA) in current atmospheric models. In this study, we …

Chemical characterization of secondary organic aerosol from oxidation of isoprene hydroxyhydroperoxides

M Riva, SH Budisulistiorini, Y Chen… - … science & technology, 2016 - ACS Publications
Atmospheric oxidation of isoprene under low-NO x conditions leads to the formation of
isoprene hydroxyhydroperoxides (ISOPOOH). Subsequent oxidation of ISOPOOH largely …

Organosulfates in Atlanta, Georgia: anthropogenic influences on biogenic secondary organic aerosol formation

APS Hettiyadura, IM Al-Naiema… - Atmospheric …, 2019 - acp.copernicus.org
Organosulfates are secondary organic aerosol (SOA) products that form from reactions of
volatile organic compounds (VOC), such as isoprene, in the presence of sulfate that is …

Chemical characteristics of organic aerosols in Shanghai: A study by ultrahigh‐performance liquid chromatography coupled with Orbitrap mass spectrometry

X Wang, N Hayeck, M Brüggemann… - Journal of …, 2017 - Wiley Online Library
Abstract Particulate matter 2.5 (PM2. 5) filter samples were collected in July and October
2014 and January and April 2015 in urban Shanghai and analyzed using ultrahigh …

Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes

M Riva, T Da Silva Barbosa, YH Lin… - Atmospheric …, 2016 - acp.copernicus.org
We report the formation of aliphatic organosulfates (OSs) in secondary organic aerosol
(SOA) from the photooxidation of C 10–C 12 alkanes. The results complement those from …

Assessing the impact of anthropogenic pollution on isoprene-derived secondary organic aerosol formation in PM2.5 collected from the Birmingham, Alabama …

W Rattanavaraha, K Chu… - Atmospheric …, 2016 - acp.copernicus.org
In the southeastern US, substantial emissions of isoprene from deciduous trees undergo
atmospheric oxidation to form secondary organic aerosol (SOA) that contributes to fine …