Organophosphorus compounds hold significant importance in the fields of materials
science, medicinal chemistry, pesticides and organic synthesis. In particular, phosphonate …

Organosulfur compounds, especially sulfur ylides and sulfonium salts, offer extraordinary
potential in organic chemistry due to their distinctive structural properties and reactivities. In …

Here we report the design of a general, redox-switchable organophosphorus alkyl radical
trap that enables the synthesis of a broad range of C (sp 3)–P (V) modalities. This “plug-and …

Here we report a visible-light facilitated radical addition strategy for the preparation of
various natural or unnatural α-amino acids from readily available glycine derivatives and …

Organophosphate analogues are commonly occurring structural features that are widely
present in numerous natural substances, biologically active molecules and modern …

Antibacterial resistance is a severe threat to modern medicine and human health. To stay
ahead of constantly-evolving bacteria we need to expand our arsenal of effective antibiotics …

A highly atom-economic (2+ 2+ 1)-cyclization of glycine derivatives with alkenes and CO2
facilitated by visible light catalysis is described. A range of multisubstituted pyrrolidones …

Here, an unprecedented formal deformylative phosphonylation is disclosed. Under the
catalysis of 1 mol% 1, 2, 3, 5-tetrakis (diphenylamino)-4, 6-dicyanobenzene (4DPAIPN) and …

We report intra-and intermolecular γ-amino C (sp3)–H functionalization of aliphatic amines
using a vinylsulfone-based HAT (hydrogen atom transfer) auxiliary and a triple catalysis …

Polyanionic antisense oligonucleotides hold great promise as RNA targeting drugs but
issues with bioavailability hinder their development. Uncharged phosphorus-based …