The use of mechanical forces to chemically transform polymers dates back decades. In recent years, the use of mechanochemistry to direct constructive transformations in polymers …
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of mechanophores that translate mechanical energy into a variety of functional responses …
IM Klein, CC Husic, DP Kovács… - Journal of the …, 2020 - ACS Publications
The development of force-responsive molecules called mechanophores is a central component of the field of polymer mechanochemistry. Mechanophores enable the design …
Z Zhang, W You, P Li, J Zhao, Z Guo, T Xu… - Journal of the …, 2022 - ACS Publications
Mimicking filament sliding in sarcomeres using artificial molecular muscles such as [c 2] daisy chains has aroused increasing interest in developing advanced polymeric materials …
Y Sagara, H Traeger, J Li, Y Okado… - Journal of the …, 2021 - ACS Publications
A new approach to cyclophane-based supramolecular mechanophores is presented. We report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical events through optical signals. Here we report rotaxane-based supramolecular …
R Hertel, W Maftuhin, M Walter… - Journal of the American …, 2022 - ACS Publications
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD) springs allow sensing of forces acting on polymer chains by monotonic changes of …
QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of research that is emerging out of the confluence of chemical topology with the mechanical …
T Muramatsu, S Shimizu, JM Clough… - … Applied Materials & …, 2023 - ACS Publications
The molecular shuttling function of rotaxanes can be exploited to design mechanoresponsive reporter molecules. Here, we report a new approach to such rotaxane …