Small molecules have extensive untapped potential to benefit society, but access to this
potential is too often restricted by limitations inherent to the highly customized approach that …

As one of the effective strategies for carbohydrate synthesis, chemical synthesis can
precisely control the structure of sugar chains, thus establishing the structure-activity …

We disclose unprecedented synergistic bimetallic Ni/Ag and Ni/Cu catalysts for
regioselective γ, δ-diarylation of unactivated alkenes in simple ketimines with aryl halides …

Single‐electron transfer (SET) oxidation of ionic hypervalent complexes, in particular
alkyltrifluoroborates (Alkyl‐BF3−) and alkylbis (catecholato) silicates (Alkyl‐Si (cat) 2−), have …

In the past few decades, palladium-catalyzed cross-coupling reactions have taken root in the
construction of a complex synthetic community. The development of organometallics has …

Advances in Pd-catalysed cross-coupling reactions have facilitated the development of
stereospecific variants enabling the use of configurationally stable, enantioenriched, main …

The Stille cross‐coupling reaction is one of the most common strategies for the construction
of C− C bonds. Despite notable strides in the advancement of the Stille reaction, persistent …

A novel strategy for the stereospecific Pd-catalyzed acylative cross-coupling of
enantiomerically enriched alkylboron compounds has been developed. The protocol …

Pd-catalyzed cross-coupling reactions have achieved tremendous accomplishments in the
past decades. However, C (sp3)-hybridized nucleophiles generally remain as challenging …

Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters
undergo stereospecific radical‐induced 1, 2‐migration in radical polar crossover reactions …