Oxygen Evolution/Reduction Reaction Catalysts: From In Situ Monitoring and Reaction Mechanisms to Rational Design

Y Zhao, DP Adiyeri Saseendran, C Huang… - Chemical …, 2023 - ACS Publications
The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are core steps of
various energy conversion and storage systems. However, their sluggish reaction kinetics …

Photoactive iron complexes: more sustainable, but still a challenge

P Dierks, Y Vukadinovic, M Bauer - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
On transition metals such as iron rests lots of hope to replace precious metal catalysts in the
field of photochemistry for a more sustainable future. Indeed, significant progress has been …

Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States

O Prakash, L Lindh, N Kaul, NW Rosemann… - Inorganic …, 2022 - ACS Publications
Fe (III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …

[HTML][HTML] Photofunctionality of iron (III) N-heterocyclic carbenes and related d5 transition metal complexes

P Chábera, L Lindh, NW Rosemann, O Prakash… - Coordination Chemistry …, 2021 - Elsevier
Despite a few reports of photoluminescent and strongly photo-oxidizing transition metal
complexes with ad 5 electronic configuration, the photophysics and photochemistry of this …

Transition metal complexes of thiosemicarbazides, thiocarbohydrazides, and their corresponding carbazones with Cu (I), Cu (II), Co (II), Ni (II), Pd (II), and Ag (I)—A …

AA Aly, EM Abdallah, SA Ahmed, MM Rabee, S Bräse - Molecules, 2023 - mdpi.com
This review focuses on some interesting and recent applications of transition metals towards
the complexation of thiosemicarbazides, thiocarbohydrazides, and their corresponding …

Microsecond photoluminescence and photoreactivity of a metal-centered excited state in a hexacarbene–Co (III) complex

S Kaufhold, NW Rosemann, P Chabera… - Journal of the …, 2021 - ACS Publications
The photofunctionality of the cobalt–hexacarbene complex [Co (III)(PhB (MeIm) 3) 2]+(PhB
(MeIm) 3= tris (3-methylimidazolin-2-ylidene)(phenyl) borate) has been investigated by time …

Can range-separated functionals be optimally tuned to predict spectra and excited state dynamics in photoactive iron complexes?

JP Zobel, A Kruse, O Baig, S Lochbrunner… - Chemical …, 2023 - pubs.rsc.org
Density functional theory is an efficient computational tool to investigate photophysical and
photochemical processes in transition metal complexes, giving invaluable assistance in …

Multifaceted Deactivation Dynamics of Fe(II) N-Heterocyclic Carbene Photosensitizers

L Lindh, T Pascher, S Persson, Y Goriya… - The Journal of …, 2023 - ACS Publications
Excited state dynamics of three iron (II) carbene complexes that serve as prototype Earth-
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …

Ultrafast Spectroscopy of Fe (II) Complexes Designed for Solar‐Energy Conversion: Current Status and Open Questions

C Cebrián, M Pastore, A Monari, X Assfeld… - …, 2022 - Wiley Online Library
One major challenge of future sustainable photochemistry is to replace precious and rare
transition metals in applications such as energy conversion or electroluminescence by earth …

Photochemical and photophysical dynamics of the aqueous ferrate (VI) ion

C Antolini, CD Spellman Jr, CJ Otolski… - Journal of the …, 2022 - ACS Publications
Ferrate (VI) has the potential to play a key role in future water supplies. Its salts have been
suggested as “green” alternatives to current advanced oxidation and disinfection methods in …