Paving the way for lignin valorisation: recent advances in bioengineering, biorefining and catalysis

R Rinaldi, R Jastrzebski, MT Clough… - Angewandte Chemie …, 2016 - Wiley Online Library
Lignin is an abundant biopolymer with a high carbon content and high aromaticity. Despite
its potential as a raw material for the fuel and chemical industries, lignin remains the most …

A critical review on hemicellulose pyrolysis

X Zhou, W Li, R Mabon, LJ Broadbelt - Energy Technology, 2017 - Wiley Online Library
Fast pyrolysis is a promising thermochemical technology that breaks down renewable and
abundant lignocellulosic biomass into a primary liquid product (bio‐oil) in seconds. The bio …

Carbohydrate-aromatic interface and molecular architecture of lignocellulose

A Kirui, W Zhao, F Deligey, H Yang, X Kang… - Nature …, 2022 - nature.com
Plant cell walls constitute the majority of lignocellulosic biomass and serve as a renewable
resource of biomaterials and biofuel. Extensive interactions between polysaccharides and …

Recent advances in characterization of lignin polymer by solution-state nuclear magnetic resonance (NMR) methodology

JL Wen, SL Sun, BL Xue, RC Sun - Materials, 2013 - mdpi.com
The demand for efficient utilization of biomass induces a detailed analysis of the
fundamental chemical structures of biomass, especially the complex structures of lignin …

Pre-treatment of lignocellulosic feedstocks using biorenewable alcohols: towards complete biomass valorisation

CS Lancefield, I Panovic, PJ Deuss, K Barta… - Green …, 2017 - pubs.rsc.org
Here, we report on the ability of the biomass derived solvents ethanol and, in particular, n-
butanol to fractionate lignocellulose into its main components. An organosolv system …

Catalytic biorefining of plant biomass to non‐pyrolytic lignin bio‐oil and carbohydrates through hydrogen transfer reactions

P Ferrini, R Rinaldi - Angewandte Chemie, 2014 - Wiley Online Library
Through catalytic hydrogen transfer reactions, a new biorefining method results in the
isolation of depolymerized lignin—a non‐pyrolytic lignin bio‐oil—in addition to pulps that …

Investigation of lignin deposition on cellulose during hydrothermal pretreatment, its effect on cellulose hydrolysis, and underlying mechanisms

H Li, Y Pu, R Kumar, AJ Ragauskas… - Biotechnology and …, 2014 - Wiley Online Library
In dilute acid pretreatment of lignocellulosic biomass, lignin has been shown to form droplets
that deposit on the cellulose surface and retard enzymatic digestion of cellulose (Donohoe …

From plant biomass to bio-based chemicals: latest developments in xylan research

R Deutschmann, RFH Dekker - Biotechnology advances, 2012 - Elsevier
For a hundred years or more, oil and natural gas has supplied fuel and other raw chemicals
to support economic growth. In the last decades their shrinking reservoirs and the increasing …

The fate of lignin during hydrothermal pretreatment

HL Trajano, NL Engle, M Foston, AJ Ragauskas… - Biotechnology for …, 2013 - Springer
Background Effective enzymatic hydrolysis of lignocellulosic biomass benefits from lignin
removal, relocation, and/or modification during hydrothermal pretreatment. Phase transition …

Comparison of different biomass pretreatment techniques and their impact on chemistry and structure

S Singh, G Cheng, N Sathitsuksanoh, D Wu… - Frontiers in Energy …, 2015 - frontiersin.org
Pretreatment of lignocellulosic biomass is a prerequisite to overcome recalcitrance and
allow enzyme accessibility to cellulose and maximize product recovery for improved …