Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence

EV Chernikova, KO Mineeva - Polymer Science, Series C, 2022 - Springer
The review addresses the synthesis of copolymers with the controlled distribution of
monomer units (random, gradient, block-random, block-gradient, multiblock copolymers) by …

Monte Carlo simulation of surface-initiated polymerization: heterogeneous reaction environment

B Yang, S Liu, J Ma, Y Yang, J Li, BP Jiang, S Ji… - …, 2022 - ACS Publications
Computer simulations are widely applied to study surface-initiated polymerization (SIP), but
in many studies, the chains are assumed to grow at the same speed, implying a …

Modern Trends in Polymerization-Induced Self-Assembly

NS Serkhacheva, NI Prokopov, EA Lysenko… - Polymers, 2024 - mdpi.com
Polymerization-induced self-assembly (PISA) is a powerful and versatile technique for
producing colloidal dispersions of block copolymer particles with desired morphologies …

RAFT copolymerization of vinyl acetate and acrylic acid in the selective solvent

EY Kozhunova, AV Plutalova, EV Chernikova - Polymers, 2022 - mdpi.com
Reversible addition-fragmentation chain transfer polymerization was successfully applied to
the synthesis of the gradient copolymer of acrylic acid and vinyl acetate in the selective …

Copolymerization of partly incompatible monomers: An insight from computer simulations

AA Gavrilov, AV Chertovich - Macromolecules, 2017 - ACS Publications
We used dissipative particle dynamics simulations to study the copolymerization process in
the presence of spatial heterogeneities caused by incompatibility between polymerizing …

Simulation of the RAFT polymerization in 3D: Steric restrictions and incompatibility between species

AA Gavrilov, AV Chertovich - Polymer Chemistry, 2022 - pubs.rsc.org
In this work we developed a RAFT polymerization model taking into account the main
reactions of the experimental RAFT process and implemented that model in dissipative …

A simple stochastic reaction model for heterogeneous polymerizations

J Ma, J Li, B Yang, S Liu, BP Jiang, S Ji, XC Shen - Polymers, 2022 - mdpi.com
The stochastic reaction model (SRM) treats polymerization as a pure probability‐based
issue, which is widely applied to simulate various polymerization processes. However, in …

Polymerization-induced phase separation in gradient copolymers

MY Zaremski, EY Kozhunova, SS Abramchuk… - Mendeleev …, 2021 - mathnet.ru
Gradient copolymers of styrene and N-vinylpyrrolidone, obtained in bulk using the reversible
deactivation radical polymerization process under the action of TEMPO nitroxide, can form …

Phase Diagram for Ideal Diblock-Copolymer Micelles Compared to Polymerization-Induced Self Assembly

AA Gavrilov, RM Shupanov, AV Chertovich - Polymers, 2020 - mdpi.com
In this work we constructed a detailed phase diagram for the solutions of ideal diblock-
copolymers and compared such diagram with that obtained during polymerization-induced …

A new porous copolymer electrocatalyst: the optimal synthesis, characterization, and application for the measurement of amoxicillin

A Farshadinia, M Kolahdoozan - Journal of Applied Electrochemistry, 2019 - Springer
The poly (diphenylamine) and poly (4, 4′-diaminodiphenyl ether) represent poor current
signals and activity. This paper has aimed to synthesize the poly (diphenylamine-co-4, 4 …