The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

The high affinity of sulfur (S) for transition metal ions (M), as well as the flexible M− S
bonding and bridging modes, enable the formation of a wide range of multi-metallic …

This perspective article focuses its attention on the most recent advances in
hydrodefluorination processes catalyzed by late transition metal complexes, a field that has …

In this review, transformations of C–F to C–X bonds mediated by transition-metal complexes
are considered from the ligand's perspective. In C–F bond activation reactions, the ligands …

A transition‐metal‐free catalytic hydrodefluorination (HDF) reaction of polyfluoroarenes is
described. The reaction involves direct hydride transfer from a hydrosilicate as the key …

Transition metal (TM)-based catalysts are indispensable tools in modern organic synthesis.
Although many efficient catalysts based on TMs are already known, further improvement of …

The development of a safe and efficient method for the degradation of SF6 is of current
environmental interest, because SF6 is one of the most potent greenhouse gases. SF6 is …

Abstract Die Aktivierung und Funktionalisierung von Kohlenstoff‐Fluor‐Bindungen ist eine
der großen Herausforderungen für die metallorganische Chemie. Der steigende Bedarf an …

The hydrodefluorination (HDF) of fluoroalkenes in the presence of a variety of titanium
catalysts was studied with respect to scope, selectivity, and mechanism. Optimization …

Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …