Organoboron-based multiple-resonance emitters: synthesis, structure–property correlations, and prospects

M Mamada, M Hayakawa, J Ochi… - Chemical Society …, 2024 - pubs.rsc.org
Boron-based multiple-resonance (MR) emitters exhibit the advantages of narrowband
emission, high absolute photoluminescence quantum yield, thermally activated delayed …

Silylium Ions: From Elusive Reactive Intermediates to Potent Catalysts

HFT Klare, L Albers, L Süsse, S Keess… - Chemical …, 2021 - ACS Publications
The history of silyl cations has all the makings of a drama but with a happy ending. Being
considered reactive intermediates impossible to isolate in the condensed phase for …

Sequential multiple borylation toward an ultrapure green thermally activated delayed fluorescence material

S Uemura, S Oda, M Hayakawa… - Journal of the …, 2022 - ACS Publications
Multiple-resonance thermally activated delayed fluorescence (MR-TADF) emitters have
emerged as an important component of organic light-emitting diodes (OLEDs) because of …

Metallomimetic chemistry of boron

MA Légaré, C Pranckevicius, H Braunschweig - Chemical reviews, 2019 - ACS Publications
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

Lewis superacids: classifications, candidates, and applications

L Greb - Chemistry–A European Journal, 2018 - Wiley Online Library
Lewis acids play a major role in all areas of chemistry. For a long time, toxic, corrosive and
oxidizing SbF5 was considered as the strongest Lewis acid known. Lately, species …

31P NMR Chemical Shifts of Phosphorus Probes as Reliable and Practical Acidity Scales for Solid and Liquid Catalysts

A Zheng, SB Liu, F Deng - Chemical reviews, 2017 - ACS Publications
Acid–base catalytic reaction, either in heterogeneous or homogeneous systems, is one of
the most important chemical reactions that has provoked a wide variety of industrial catalytic …

Regioselective Transition‐Metal‐Free C(sp2)−H Borylation: A Subject of Practical and Ongoing Interest in Synthetic Organic Chemistry

S Rej, N Chatani - Angewandte Chemie International Edition, 2022 - Wiley Online Library
Considerable advances have been made in the area of C− H functionalization in the last few
decades. A number of approaches including both directed and nondirected strategies have …

Metal-free catalytic CH bond activation and borylation of heteroarenes

MA Légaré, MA Courtemanche, É Rochette… - Science, 2015 - science.org
Transition metal complexes are efficient catalysts for the CH bond functionalization of
heteroarenes to generate useful products for the pharmaceutical and agricultural industries …

Recent advances in catalytic C− H borylation reactions

L Xu, G Wang, S Zhang, H Wang, L Wang, L Liu, J Jiao… - Tetrahedron, 2017 - Elsevier
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …

Reactive p-block cations stabilized by weakly coordinating anions

TA Engesser, MR Lichtenthaler, M Schleep… - Chemical Society …, 2016 - pubs.rsc.org
The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …