Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

Multifunctional π-expanded oligothiophene macrocycles

M Iyoda, H Shimizu - Chemical Society Reviews, 2015 - pubs.rsc.org
This tutorial review summarizes recent progress in the design, synthesis, and multifunctional
properties of fully conjugated macrocyclic π-systems. We focus on the π-expanded …

Polaritons and excitons: Hamiltonian design for enhanced coherence

GD Scholes - Proceedings of the Royal Society A, 2020 - royalsocietypublishing.org
The primary questions motivating this report are: Are there ways to increase coherence and
delocalization of excitation among many molecules at moderate electronic coupling …

Superhalogen doping: a new and effective approach to design materials with excellent static and dynamic NLO responses

H Sajid, F Ullah, M Yar, K Ayub… - New Journal of Chemistry, 2020 - pubs.rsc.org
Excess electron generation through doping with alkali and superalkali metals is well known
to enhance NLO responses. On the contrary, superhalogen doping is an unexplored …

Infinitene: Computational insights from nonadiabatic excited state dynamics

VM Freixas, S Tretiak… - The Journal of Physical …, 2022 - ACS Publications
Progress in organic synthesis opens exploration of a rich diversity of molecules with
interesting new structural topologies. This is the case of a recently synthesized helically …

Strained Porphyrin Tape–Cycloparaphenylene Hybrid Nanorings

W Stawski, JM Van Raden, CW Patrick… - Organic …, 2023 - ACS Publications
V-Shaped porphyrin dimers, with masked p-phenylene bridges, undergo efficient oxidative
coupling to form meso–meso linked cyclic porphyrin oligomers. Reductive aromatization …

Modulation of symmetry-breaking intramolecular charge-transfer dynamics assisted by pendant side chains in π-linkers in quadrupolar diketopyrrolopyrrole …

W Kim, J Sung, M Grzybowski, DT Gryko… - The Journal of Physical …, 2016 - ACS Publications
The effect of the length of pendant side chains in centrosymmetric quadrupolar molecules on
dynamics of their most perplexing photophysical phenomenon, ie, symmetry-breaking …

Excited-state structural relaxation and exciton delocalization dynamics in linear and cyclic π-conjugated oligothiophenes

KH Park, W Kim, J Yang, D Kim - Chemical Society Reviews, 2018 - pubs.rsc.org
π-Conjugated oligothiophene is considered a chain segment of its polymeric counterpart,
whose size and shape can be precisely controlled. Because of its simplified structure, it is …

Torsional disorder and planarization dynamics: 9, 10-bis (phenylethynyl) anthracene as a case study

I Fureraj, DS Budkina, E Vauthey - Physical Chemistry Chemical …, 2022 - pubs.rsc.org
Conjugated molecules with phenylethynyl building blocks are usually characterised by
torsional disorder at room temperature. They are much more rigid in the electronic excited …

Structural relaxation of photoexcited quaterthiophenes probed with vibrational specificity

J Zhou, W Yu, AE Bragg - The journal of physical chemistry letters, 2015 - ACS Publications
Ultrafast structural relaxation of photoexcited 2, 2′: 5′, 2 ″: 5 ″, 2‴-quaterthiophene (4T)
and 3, 3‴-Dihexyl-2, 2′: 5′, 2 ″: 5 ″, 2‴-quaterthiophene (DH4T) in solution were …