Since ferrocene was first obtained as the product of attempts to synthesize fulvalene by the
coupling of cyclopentadienylmagnesium bromide over iron (III) chloride, 1 a great deal of …

Abstract Polysiloxanes [ R2Si O] n, polyphosphazenes [ R2P N] n, and polysilanes
[ R2Si] n illustrate that the incorporation of inorganic elements into a polymer main chain …

Planar-chiral ferrocenes are widely applied in catalytic asymmetric transformations in
scientific research as well as in industry. A plethora of different methodologies have been …

The living anionic ring-opening polymerization (ROP) of the methylated silicon-bridged [1]
ferrocenophane Fe (η-C5H4) 2SiMe2 1 initiated by n-BuLi, PhLi, FcLi (Fc= Fe (η-C5H4)(η …

In order to gain insight into the electrochemical and conformational properties of the
prototypical high polymeric poly (ferrocenylsilane), poly (ferrocenyldimethylsilane)[Fe (η …

The study of metallopolymers has blossomed into a mature field over the last few decades.
Especially, polyferrocenylsilane (PFS) chemistry has taken a tremendous leap and …

Electropolymerization of monomers containing both transition metals and thiophene, and the
properties of the resulting materials are reviewed. Polymers with metal centers linked to the …

The past 20 years has witnessed an explosion in the field of organic based materials
chemistry. There has been a push to incorporate transition metal complexes from all over the …

This article provides a comprehensive review of the synthesis, properties and applications of
organometallic polymers of the transition metals. The different classes of organometallic …

The vinylene-bridged ansa-ferrocene complex [(η5-C5H4) CH CH (η5-C5H4)] Fe (1) was
synthesized by the McMurry coupling of 1, 1 '-ferrocenedicarbaldehyde (2). The ring opening …