Recent advances in ruthenium-based olefin metathesis

OM Ogba, NC Warner, DJ O'leary… - Chemical Society …, 2018 - pubs.rsc.org
Ruthenium-based olefin metathesis catalysts, known for their functional group tolerance and
broad applicability in organic synthesis and polymer science, continue to evolve as an …

The synthesis, properties and potential applications of cyclic polymers

FM Haque, SM Grayson - Nature Chemistry, 2020 - nature.com
Unlike their more common linear counterparts, cyclic polymers have a ring-like structure and
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …

A synthetic polymer system with repeatable chemical recyclability

JB Zhu, EM Watson, J Tang, EYX Chen - Science, 2018 - science.org
The development of chemically recyclable polymers offers a solution to the end-of-use issue
of polymeric materials and provides a closed-loop approach toward a circular materials …

Molecular bottlebrushes as novel materials

G Xie, MR Martinez, M Olszewski, SS Sheiko… - …, 2018 - ACS Publications
Molecular bottlebrushes are building blocks for the design of unique polymeric materials
whose physical properties are fundamentally governed by their densely grafted structures …

Recent trends in catalytic polymerizations

DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …

Completely recyclable biopolymers with linear and cyclic topologies via ring-opening polymerization of γ-butyrolactone

M Hong, EYX Chen - Nature Chemistry, 2016 - nature.com
Ring-opening polymerization (ROP) is a powerful synthetic methodology for the chemical
synthesis of technologically important biodegradable aliphatic polyesters from cyclic esters …

Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair

Y Song, J He, Y Zhang, RA Gilsdorf, EYX Chen - Nature Chemistry, 2023 - nature.com
The existing catalyst/initiator systems and methodologies used for the synthesis of polymers
can access only a few cyclic polymers composed entirely of a single monomer type, and the …

Architecture-transformable polymers: Reshaping the future of stimuli-responsive polymers

H Sun, CP Kabb, MB Sims, BS Sumerlin - Progress in Polymer Science, 2019 - Elsevier
The field of stimuli-responsive, or smart polymers, has commanded significant interest over
the past decade. However, most examples of stimuli-responsive polymers have relied on …

BigSMILES: a structurally-based line notation for describing macromolecules

TS Lin, CW Coley, H Mochigase, HK Beech… - ACS central …, 2019 - ACS Publications
Having a compact yet robust structurally based identifier or representation system is a key
enabling factor for efficient sharing and dissemination of research results within the …

Poly[n]catenanes: Synthesis of molecular interlocked chains

Q Wu, PM Rauscher, X Lang, RJ Wojtecki, JJ De Pablo… - Science, 2017 - science.org
As the macromolecular version of mechanically interlocked molecules, mechanically
interlocked polymers are promising candidates for the creation of sophisticated molecular …