Chemistry under high pressure

M Miao, Y Sun, E Zurek, H Lin - Nature Reviews Chemistry, 2020 - nature.com
Thanks to the development of experimental high-pressure techniques and methods for
crystal-structure prediction based on quantum mechanics, in the past decade, numerous …

Two-dimensional ultrathin silica films

JQ Zhong, HJ Freund - Chemical Reviews, 2022 - ACS Publications
Two-dimensional (2D) ultrathin silica films have the potential to reach technological
importance in electronics and catalysis. Several well-defined 2D-silica structures have been …

Computational prediction of boron-based MAX phases and MXene derivatives

N Miao, J Wang, Y Gong, J Wu, H Niu… - Chemistry of …, 2020 - ACS Publications
Conventional MAX phases (M is an early transition metal, A represents a p-block element or
Cd, and X is carbon or nitrogen) have so far been limited to carbides and/or nitrides. In the …

Reactions of xenon with iron and nickel are predicted in the Earth's inner core

L Zhu, H Liu, CJ Pickard, G Zou, Y Ma - Nature chemistry, 2014 - nature.com
Studies of the Earth's atmosphere have shown that more than 90% of the expected amount
of Xe is depleted, a finding often referred to as the 'missing Xe paradox'. Although several …

A stable compound of helium and sodium at high pressure

X Dong, AR Oganov, AF Goncharov, E Stavrou… - Nature Chemistry, 2017 - nature.com
Helium is generally understood to be chemically inert and this is due to its extremely stable
closed-shell electronic configuration, zero electron affinity and an unsurpassed ionization …

Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

Y Yun, M Wu, C Xie, Z Yang, G Li… - Advanced Optical …, 2023 - Wiley Online Library
NaSrBS3, the first noncentrosymmetric alkali and alkaline earth metal mixed thioborate with
the isolated [BS3] as the building units, has been synthesized successfully under the …

Prediction of fluorooxoborates with colossal second harmonic generation (SHG) coefficients and extremely wide band gaps: Towards modulating properties by tuning …

B Zhang, E Tikhonov, C Xie, Z Yang… - Angewandte …, 2019 - Wiley Online Library
Fluorooxoborates have inspired investigations of deep‐ultraviolet (DUV) nonlinear optical
(NLO) materials that can meet the multiple criteria. Herein, five stable structures with the …

Synthesis and stability of xenon oxides Xe2O5 and Xe3O2 under pressure

A Dewaele, N Worth, CJ Pickard, RJ Needs… - Nature …, 2016 - nature.com
The noble gases are the most inert group of the periodic table, but their reactivity increases
with pressure. Diamond-anvil-cell experiments and ab initio modelling have been used to …

Xenon iron oxides predicted as potential Xe hosts in Earth's lower mantle

F Peng, X Song, C Liu, Q Li, M Miao, C Chen… - Nature …, 2020 - nature.com
An enduring geological mystery concerns the missing xenon problem, referring to the
abnormally low concentration of xenon compared to other noble gases in Earth's …

Anionic chemistry of noble gases: formation of Mg–NG (NG= Xe, Kr, Ar) compounds under pressure

M Miao, X Wang, J Brgoch, F Spera… - Journal of the …, 2015 - ACS Publications
While often considered to be chemically inert, the reactivity of noble gas elements at
elevated pressures is an important aspect of fundamental chemistry. The discovery of Xe …