Formazanate coordination compounds: synthesis, reactivity, and applications
Formazans (Ar1-NH-NCR3-NN-Ar5), a class of nitrogen-rich and highly colored compounds,
have been known since the late 1800s and studied more closely since the early 1940s …
have been known since the late 1800s and studied more closely since the early 1940s …
Photostable small-molecule NIR-II fluorescent scaffolds that cross the blood–brain barrier for noninvasive brain imaging
The second near-infrared (NIR-II, 1000–1700 nm) fluorescent probes have significant
advantages over visible or NIR-I (600–900 nm) imaging for both depth of penetration and …
advantages over visible or NIR-I (600–900 nm) imaging for both depth of penetration and …
Self-assembled organic nanomedicine enables ultrastable photo-to-heat converting theranostics in the second near-infrared biowindow
Abstract Development of organic theranostic agents that are active in the second near-
infrared (NIR-II, 1000–1700 nm) biowindow is of vital significance for treating deep-seated …
infrared (NIR-II, 1000–1700 nm) biowindow is of vital significance for treating deep-seated …
Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands
JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …
importance for selective (catalytic) processes. This Concept aims to provide an overview of …
Advancements in boron difluoride formazanate dyes for biological imaging
In the past decade, boron difluoride formazanate dyes have gained considerable attention
due to their redox activity, high absorption and emission intensities, chemical stability across …
due to their redox activity, high absorption and emission intensities, chemical stability across …
Near‐infrared photoluminescence and electrochemiluminescence from a remarkably simple boron difluoride formazanate dye
A boron difluoride formazanate dye that exhibits near‐infrared photoluminescence and
electrochemiluminescence was produced via a straightforward two‐step synthesis …
electrochemiluminescence was produced via a straightforward two‐step synthesis …
Boron difluorides with formazanate ligands: redox-switchable fluorescent dyes with large stokes shifts
The synthesis of a series of (formazanate) boron difluorides and their 1-electron reduction
products is described. The neutral compounds are fluorescent with large Stokes shifts. DFT …
products is described. The neutral compounds are fluorescent with large Stokes shifts. DFT …
WORM type memory device based on ionic organotin complex using 1, 5-diphenyl-3-(2-pyridyl) formazan ligand
Synthesis, structure, and write once read many (WORM) type memory behavior of an ionic
organotin complex containing a 2-pyridine substituted formazan ligand is described herein …
organotin complex containing a 2-pyridine substituted formazan ligand is described herein …
π-conjugated copolymers composed of boron formazanate and their application for a wavelength converter to near-infrared light
Y Kawano, Y Ito, S Ito, K Tanaka, Y Chujo - Macromolecules, 2021 - ACS Publications
We report conjugated polymers consisting of boron formazanate in the main chains. By
employing typical donor-type comonomers, such as fluorene and bithiophene, copolymers …
employing typical donor-type comonomers, such as fluorene and bithiophene, copolymers …
A π-conjugated inorganic polymer constructed from boron difluoride formazanates and platinum (ii) diynes
The first example of a π-conjugated polymer incorporating boron difluoride (BF2)
formazanates is introduced. The film-forming properties, controllable reduction chemistry …
formazanates is introduced. The film-forming properties, controllable reduction chemistry …