Ionic liquids and deep eutectic solvents are of growing interest as solvents for the resource‐
efficient synthesis of inorganic materials. This Review covers chemical reactions of various …

Clusters have been the subject of intense investigations since their famous definition
launched by Cotton in 1963, and the area has expanded ever since. One obvious …

Conspectus Bismuth-based research has become a highly topical field in recent years,
yielding remarkable prospects for new fundamental insights and new materials applications …

Nanoarrays (NAs) with stable signal output have become the most promising
photoelectrochemical (PEC) biosensing substrate. However, a general issue is that …

In contrast to their lighter homologues (P, As, Sb), the synthesis of polybismuthane clusters
is still restricted to classical solid-state approaches. We herein report on systematic …

Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model
systems to study fundamental structure and bonding situations of compositionally related …

Bismuth-rich polyanions show a unique potential in constructing nanostructured bismuth-
based materials, but they are still poorly investigated. We use a ternary precursor of the …

Bismuth polycations have garnered significant attention from researchers due to their
extraordinary and counter‐intuitive structures and stoichiometries. Despite extensive …

[Bi 6 Mo 3 (CO) 9 ] 4− : a multiple local σ-aromatic cluster containing a distorted Bi 6 triangular
prism - Chemical Communications (RSC Publishing) DOI:10.1039/D1CC00734C Royal …

The reaction of Ag2O, Au2O3, and HgO with CuCl, CuI, AgCl, AgI, AuCl, and AuI in ionic
liquids ([EMIm] Cl,[BMIm] Cl) near room temperature (20–80° C) is evaluated and results in …