Recent progress in trivalent actinide and lanthanide solvent extraction and coordination chemistry with triazinylpyridine N donor ligands

A Geist, PJ Panak - Solvent Extraction and Ion Exchange, 2021 - Taylor & Francis
ABSTRACT A follow up to an earlier review on the coordination and extraction of trivalent
actinide and lanthanide ions with triazinylpyridine N-donor ligands is presented. It reviews …

Computational Tools and Techniques in Designing Ligands for the Selective Separation of Actinide and Lanthanide: A Review

C Ebenezer, RV Solomon - Comments on Inorganic Chemistry, 2024 - Taylor & Francis
The development of density functional theory (DFT) has significantly enhanced the use of
computational chemistry as a tool in the design and development of ligands for the …

Theoretical insights into phenanthroline-based ligands toward the separation of Am (III)/Eu (III)

Y Zou, JH Lan, LY Yuan, CZ Wang, QY Wu… - Inorganic …, 2022 - ACS Publications
The bistriazinyl-phenanthroline representative ligand, BTPhen, shows excellent extraction
and separation ability for trivalent actinides and lanthanides. Herein, we first designed three …

Coordination of actinides and the chemistry behind solvent extraction

AE Clark, P Yang, JC Shafer - Experimental and Theoretical …, 2018 - Wiley Online Library
This chapter discusses in context the separations processes of actinides that involve
primarily solvent extraction. A brief overview of separations processes utilized in the early of …

Selective Separation of MA(III) from Ln(III) by Highly Stable Silica-Polymer-based N-Donor IsoBu-BTP/SiO2-P Adsorbent

S Ning, W Zhang, S Yu, S Zhang, J Zhou… - … Extraction and Ion …, 2019 - Taylor & Francis
To separate minor actinides (MA) from lanthanides from high-level liquid waste (HLLW), a
kind of micro-porous silica-polymer (SiO2-P) based N-donor iso Bu-BTP/SiO2-P adsorbent …

An experimental and theoretical analysis of supercritical carbon dioxide extraction of Cu (II) and Pb (II) ions in the form of dithizone bidentate complexes

J Halili, A Berisha - Turkish Journal of Chemistry, 2022 - journals.tubitak.gov.tr
For more than five decades, dithizone has been widely used as an analytical reagent. This
ligand forms strongly colored complexes with metal ions and this ability to form complexes …

Experimental evidence and quantum chemical insights into extraction and third phase aggregation trends in Ce (IV) organophosphates

A Chandrasekar, N Sivaraman, TK Ghanty… - Separation and …, 2019 - Elsevier
Abstract “Third phase” formation is an aggregation phenomenon that arises due to the
mutual attraction of the polar cores of reverse micelles in a non-polar medium. A major …

Theoretical study of the ability of symmetric and asymmetric N-donor ligands to separate Am (III) and Eu (III) and the bonding nature

Q Huang, S Wu, YT Liang, AY Li - Computational and Theoretical …, 2024 - Elsevier
In the reprocessing of spent nuclear fuel, nitrogen-donor extractants are more effective in
separating actinides and lanthanides. In this article, a series of heterocyclic N-donor ligands …

[图书][B] Design and Synthesis of Novel Actinide Selective Ligands for Future Spent Nuclear Fuel Reprocessing

R Bulmer - 2019 - search.proquest.com
At the end of electricity generation through nuclear power, spent nuclear fuel remains highly
radiotoxic due to the presence of the minor actinides, americium (III), curium (III) and …