Developments in the chemistry of stibine and bismuthine complexes

VK Greenacre, W Levason, G Reid - Coordination Chemistry Reviews, 2021 - Elsevier
New findings in the coordination chemistry of neutral stibine and bismuthine ligands are
reviewed. The article describes new ligand syntheses, coordination complexes of d-block …

Antimony centre in three different roles: does donor strength or acceptor ability determine the bonding pattern?

R Chlebík, C Fekete, R Jambor, A Růžička… - Dalton …, 2024 - pubs.rsc.org
A set of antimony (III) compounds containing a ligand (Ar) with a pendant guanidine function
(where Ar= 2-[(Me2N) 2CN] C6H4) was prepared and characterized. This includes triorgano …

Synthesis and non-conventional structure of square-planar Pd (II) and Pt (II) complexes with an N, C, N-chelated stibinidene ligand

M Kořenková, M Hejda, P Štěpnička, F Uhlík… - Dalton …, 2018 - pubs.rsc.org
The N, C, N-chelated stibinidene, ArSb (Ar= C6H3-2, 6-(CHNtBu) 2), reacts with Pt (II)
compounds [PtCl2L2] resulting in the formation of 1: 1 complexes, cis-[PtCl2L (ArSb)](L …

Дикарбоксилаты трис(2-метокси-5-хлорфенил)сурьмы (5-Cl-2-MeO-C6H3)3Sb[OC(O)R]2, R = CH2Br, CH2C6H4F-3, C6H3F2-2,3. Синтез и …

ВВ Шарутин, ОК Шарутина - Журнал неорганической химии, 2021 - elibrary.ru
Дикарбоксилаты< i> трис</i>(2-метокси-5-хлорфенил) сурьмы (5-Cl-2-MeO-C< sub>
6</sub> H< sub> 3</sub>)< sub> 3</sub> Sb [OC (O) R]< sub> 2</sub>, R= CH< sub> …

Tris (2-methoxy-5-chlorophenyl) antimony: Synthesis and Oxidative Addition Reactions

VV Sharutin, OK Sharutina - Russian Journal of General Chemistry, 2020 - Springer
Abstract The reaction of 2-methoxy-5-chlorophenyllithium with SbCl 3 (3: 1) in diethyl ether
has afforded tris (2-methoxy-5-chlorophenyl) antimony, which has been crystallized from …

Mixed triorganobismuthines RAr 2 Bi [Ar= C 6 F 5, 2, 4, 6-(C 6 F 5) 3 C 6 H 2] and hypervalent racemic Bi-chiral diorganobismuth (iii) bromides RArBiBr (Ar= C 6 F 5 …

M Olaru, MG Nema, A Soran, HJ Breunig… - Dalton …, 2016 - pubs.rsc.org
Triorganobismuthines R (C6F5) 2Bi (1) and R [2, 4, 6-(C6F5) 3C6H2] 2Bi (2)[R= 2-
(Me2NCH2) C6H4] were synthesized by reaction of RBiBr2 with C6F5MgBr and 2, 4, 6 …

Tris(2-metoxy-5-chlorophenyl)antimony Dicarboxylates (5-Cl-2-MeO-C6H3)3Sb[OC(O)R]2, Where R = CH2Br, CH2C6H4F-3, and C6H3F2-2,3: Synthesis …

VV Sharutin, OK Sharutina - Russian Journal of Inorganic Chemistry, 2021 - Springer
In a crystal of tris (2-methoxy-5-chlorophenyl) antimony benzene solvate (5-Cl-2-MeO-C 6 H
3) 3 Sb (I)⋅ 1/2С 6 Н 6 synthesized from SbCl 3 and 2-methoxy-5-chlorophenyllithium with …

Трис (2-метокси-5-хлорфенил) сурьма: синтез и реакции окислительного присоединения

ВВ Шарутин, ОК Шарутина - Журнал общей химии, 2020 - elibrary.ru
Взаимодействием 2-метокси-5-хлорфениллития с SbCl 3 (3: 1) в диэтиловом эфире
синтезирована трис-(2-метокси-5-хлорфенил) сурьма, кристаллизующаяся из бензола …

[PDF][PDF] Homoleptic organometallic compounds of heavy pnicogens. Crystal and molecular structure of [2-(iPr2NCH2) C6H4] 3M (M= Sb, Bi)

I Chirca, A Soran, A Silvestru, C Silvestru - Rev. Roum. Chim, 2015 - revroum.lew.ro
Two new homoleptic triorganopnicogen (III) species,[2-(iPr2NCH2) C6H4] 3M [M= Sb (2), Bi
(3)] were obtained by reacting [2-(iPr2NCH2) C6H4] MgBr (prepared in situ from [2 …

Syntheses and structural characterization of eight inorganic-organic hybrid solids based on N-Brønsted bases and halometallates of Zn, Cu, Sb and Bi

J Guo, Y Zhang, S Jin, X Ye, K Hu, W Xu… - Inorganic and Nano …, 2022 - Taylor & Francis
Eight organic-inorganic hybrid salts [(HL1)(SbCl4)](1)(L1= N, N-dimethylbenzylamine),[(HL2
) 2 (ZnCl4)](2)(L2= 4-chlorobenzylamine),[(HL2)(L2)(CuCl3)(H2O) 2](3),[(HL3) 2 …