This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-
group elements. Enantioenriched helicenic derivatives containing main-group elements B …

The catalytic asymmetric synthesis of phosphorus‐containing helicenes remains a
formidable challenge, presumably due to the lack of rational design of substrates, right …

A novel π‐extended “superhelicene” based on hexa‐peri‐hexabenzocoronenes (HBCs) has
been synthesized by an efficient four‐step synthetic procedure starting from diphenyl ether …

An enantio‐and regioconvergent allylation of phenols under nickel catalysis with an α‐/γ‐
regioisomeric mixture of racemic silylated/germylated allylic chlorides is reported. The …

Pentahelicene (PH) exhibits the largest absorption (g abs) and luminescence (g lum)
dissymmetry factors among the helicene family but is configurationally and (photo) …

A chiral phosphathiahelicene scaffold displaying a phosphole and a thiophene unit as the
terminal rings of the helical sequence has been synthesized and characterized by …

We report an organocatalyzed direct enantioselective hydrophosphonylation of N-
unsubstituted ketimines that affords N-unprotected α-tetrasubstituted α-aminophosphonates …

Helicenes are unique helical chromophores possessing advanced and well-controlled
spectral and chemical properties owing to their diverse functionalization and defined …

A series of helically shaped benzo [b] chryseno [4, 3‐d] thiophenes, naphtho [1, 2‐b]
phenanthro [4, 3‐d] thiophenes, and chryseno [3, 4‐b] naphtho [1, 2‐d] thiophenes is …