Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …

Hydrogen production through water splitting is one of the most promising solutions for the
storage of renewable energy.[NiFe] hydrogenases are organometallic enzymes containing …

The activation and selective transformation of virtually inexhaustible or easy-to-generate
chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added products is a lively …

A mononuclear, T‐shaped palladium (I) d9 metalloradical (3), stabilized by a bulky
carbazole‐based PNP‐ligand, was obtained by reduction of palladium chloride or thermal …

AT‐shaped NiI complex was synthesized using a rigid acridane‐based pincer ligand to
prepare a metalloradical center. Structural data displays a nickel ion is embedded in the …

Conspectus Nickel pincer systems have recently attracted much attention for applications in
various organometallic reactions and catalysis involving small molecule activation. Their …

Intermediate amide complexes of NHC-ligated monovalent nickel in Buchwald–Hartwig
amination of aryl halides were isolated and structurally characterized. The amide complexes …

Acetyl coenzyme A synthase (ACS) catalyzes the formation and deconstruction of the key
biological metabolite, acetyl coenzyme A (acetyl-CoA). The active site of ACS features a …

In this work, Ni (I) aryl species that are directly relevant to cross-coupling have been
synthesized. Transmetalation of (dppf) NiIX (dppf= 1, 1′-bis (diphenylphosphino) …