With the progressive increase in atmospheric CO2 over the years and owing to its potential
environmental threat, researchers have focused their attention on the fruitful utilization of …

Carbon dioxide is commonly regarded as the primary greenhouse gas, but from a synthetic
standpoint can be utilized as an alternative and sustainable C1 synthon in organic synthesis …

Carbon dioxide is a nontoxic, renewable, and abundant C1 source, whereas C− H bond
functionalization represents one of the most important approaches to the construction of …

Hydride transfer catalysis is shown to be enabled by the nonspectator reactivity of a
transition metal-bound low-symmetry tricoordinate phosphorus ligand. Complex 1·[Ru]+ …

Ligand non-innocence is ubiquitous in catalysis with ligands in synthetic complexes
contributing as electron reservoirs or co-sites for substrate activation. The latter chemical …

Metal–ligand cooperativity is a powerful tool for the activation of various bonds but has
rarely, if ever, been studied with the radioactive transition metal 99Tc. In this work, we …

Organocatalysts with carbon-centered activity for CO 2 reduction with boranes - Chemical
Communications (RSC Publishing) DOI:10.1039/C5CC04337A Royal Society of Chemistry …

Molecular main-group hydride catalysts are attractive as cheap and Earth-abundant
alternatives to transition-metal analogues. In the case of the latter, specific steric and …

Zinc (II) and cadmium (II) chlorido complexes with an N, N-chelating nopinane-annelated 4,
5-diazafluoren-9-one ligand (LO) were synthesized. While the zinc (II) complex is …

The abundance of atmospheric CO2 presents both an opportunity and a challenge for
synthetic chemists to transform CO2 into value-added products. A promising strategy …