This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

For the first-row middle transition metals (Cr, Mn, and Fe), the formal oxidation states are
relatively lower. However, biological systems in various enzymatic reactions rely extensively …

Main group chemistry is often considered less “dynamic” than transition metal (TM)
chemistry because of predictable VSEPR-based central atom geometries, relatively slower …

Three new iridium (III) corrole complexes, having symmetrically and asymmetrically
substituted corrole frameworks and judiciously varied axial ligands are prepared and …

A new tin (IV) corrole, 5, 10, 15-tris (4-methoxycarbonylphenyl) corrole tin (IV)(1-Sn) was
synthesized and characterized. The DNA binding, photocleavage and anti-cancer activity …

ABA (where A= nitrophenyl, and B= pentafluorophenyl group) corrole was isolated as
hexacoordinate P (V) complexes that contained two axial hydroxyl groups. NMR …

We present herein the synthesis of three new bis (corrolato‐ruthenium (III)) complexes
containing unsupported Ru–Ru bonds and their characterization in different redox states …

We report the stabilization of the hexa-coordination environment for P (V) corroles by using
alkyl/aryl substituted silyloxy groups as axial ligands. The P (V) corroles are highly …

A series of novel A3-corrole and trans-A2B-corroles have been synthesized with the aim of
developing organic materials with improved nonlinear optical (NLO) properties. All three …

This article covers the chemistry of corroles, tetrapyrrole macrocycles having relevance with
biologically relevant corrin ring of vitamin B12. Corroles are 18π electron aromatic systems …