The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied,
because the iron atom plays an important role in the industrial and biological nitrogen …

Transition metal–sulfur (M–S) compounds are an indispensable means for biological
systems to convert N2 into NH3 (biological N2 fixation), and these may have emerged by …

Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Nitrogenases are the enzymes by which certain microorganisms convert atmospheric
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …

The direct formation of ammonia from molecular dinitrogen under mild reaction conditions
was achieved by using new cobalt dinitrogen complexes bearing an anionic PNP‐type …

This paper describes our recent progress in catalytic nitrogen fixation by using transition-
metal–dinitrogen complexes as catalysts. Two reaction systems for the catalytic …

The Fe–S clusters of nitrogenases carry out the life-sustaining conversion of N2 to NH3.
Although progress continues to be made in modelling the structural features of nitrogenase …

The nitrogen reduction reaction (NRR) under ambient conditions using renewable energy is
a green and sustainable strategy for the synthesis of NH3, which is one of the most important …