Separation of trivalent actinides and lanthanides using various 'N','S'and mixed 'N, O'donor ligands: a review
A Bhattacharyya, PK Mohapatra - Radiochimica Acta, 2019 - degruyter.com
Separation of trivalent actinide (An) and lanthanide (Ln) elements is one of the burning
topics in the back end of the nuclear fuel cycle due to the similarity in their chemical …
topics in the back end of the nuclear fuel cycle due to the similarity in their chemical …
Unfolding the extraction and complexation behaviors of trivalent f-block elements by a tetradentate N, O-Hybrid phenanthroline derived phosphine oxide ligand
L Xu, X Yang, Z Wang, S Wang, M Sun, C Xu… - Inorganic …, 2021 - ACS Publications
In this work, a tetradentate N, O-hybrid 2, 9-bis (diphenylphosphine oxide)-1, 10-
phenanthroline (Ph2-BPPhen) ligand was studied for the coextraction of trivalent f-block …
phenanthroline (Ph2-BPPhen) ligand was studied for the coextraction of trivalent f-block …
Comparative Investigation into the Complexation and Extraction Properties of Tridentate and Tetradentate Phosphine Oxide‐Functionalized 1, 10‐Phenanthroline …
L Xu, Y Hao, X Yang, Z Wang, C Xu… - … A European Journal, 2021 - Wiley Online Library
Two new phosphine oxide‐functionalized 1, 10‐phenanthroline ligands, tetradentate 2, 9‐
bis (butylphenylphosphine oxide)‐1, 10‐phenanthroline (BuPh‐BPPhen, L1) and tridentate …
bis (butylphenylphosphine oxide)‐1, 10‐phenanthroline (BuPh‐BPPhen, L1) and tridentate …
Spectroscopic speciation of aqueous Am (III)–oxalate complexes
Transportation of actinides through the geosphere is facilitated by complexation with organic
ligands dissolved in groundwater. Carboxylic groups can interact directly with actinide ions …
ligands dissolved in groundwater. Carboxylic groups can interact directly with actinide ions …
Diglycolamic acid for the mutual separation of lanthanides and actinides from dilute nitric acid solution: solvent extraction, dynamic light scattering, and spectroscopic …
A Dhawa, J Ravi, R Puspalata, NR Jawahar… - New Journal of …, 2024 - pubs.rsc.org
N, N-Dialkyl diglycolamic acid (HDRDGA) derivatives with alkyl groups varying from n-hexyl
to n-dodecyl were synthesized, and the promising ligands such as N, N-dioctyl diglycolamic …
to n-dodecyl were synthesized, and the promising ligands such as N, N-dioctyl diglycolamic …
Thermodynamic Study of Am (III)–Isosaccharinate Complexation at Various Temperatures Implicating a Stepwise Reduction in Binding Denticity
Isosaccharinic acid, a major final product of cellulose degradation under highly alkaline
cement porewater conditions, is known to increase the mobility of actinides via strong …
cement porewater conditions, is known to increase the mobility of actinides via strong …
Complexation of thorium with pyridine monocarboxylate-N-oxides: Thermodynamic and computational studies
The feed wastes and waste water treatment plants are the major sources for the entry of N-
oxides into the soils then to aquatic life. The complexation of actinides with potentially stable …
oxides into the soils then to aquatic life. The complexation of actinides with potentially stable …
Challenges in separation processes: synthesis of nitrogen containing heterocyclic compounds as selective extracting ligands for trivalent actinides from actinides (III) …
T Gadly - Advances in Separation Sciences, 2025 - Elsevier
Soft donor ligands (containing soft donor atoms like nitrogen, sulfur, and chlorine) show
selective complexation toward the trivalent actinides due to higher spatial distribution of the …
selective complexation toward the trivalent actinides due to higher spatial distribution of the …
Solvatochromic and application in dye-sensitized solar cells of sandwich-like Cd (ii) complexes: supramolecular architectures based on N 1, N 3-bis [(6 …
XM Wang, P Wang, RQ Fan, MY Xu, LS Qiang… - Dalton …, 2015 - pubs.rsc.org
A novel polydentate Schiff base ligand N1, N3-bis [(6-methoxypyridin-2-yl) methylene]
benzene-1, 3-diamine (L) and its two dinuclear sandwich-like complexes {[CdL …
benzene-1, 3-diamine (L) and its two dinuclear sandwich-like complexes {[CdL …
Simulation of the chemical interactions of luminescent lanthanide complexes series [Ln (cin) 3 (H2O) 3]· Hcin and [Ln2 (cin) 6 (bpy) 2] using DFT calculations
MJF Martins, LF Marques, SR Tavares… - Computational Materials …, 2016 - Elsevier
In this work, DFT calculations were conducted to understand the interactions of two
luminescent complexes series, named [Ln (cin) 3 (H 2 O) 3]· Hcin and the [Ln 2 (cin) 6 (bpy) …
luminescent complexes series, named [Ln (cin) 3 (H 2 O) 3]· Hcin and the [Ln 2 (cin) 6 (bpy) …